Reactions Flashcards
When you have a negative total energy what reaction is this
Endothermic is positive
Exothermic is negative
What is activation energy
The energy required to start a reaction
Explain an exothermic reaction graph
Starts high then has the activation energy which will then make the energy decrease with the energy change being negative
Why can’t solid ionic compounds be electrolysed
Due to ions not being able to flow
Molten ionic compounds or solutions of ionic compounds can be due to ions being able to flow
Explain the electrolysis of MOLTEN compounds (PbBr)
The first part of the formula is the metal which is discharged at the cathode (so Pb will be discharged at the cathode)
The second part of the equation is the non metal which is discharged at the anode (Br) this returns back to its elemental name (bromide - bromine)
What is discharged at the cathode and anode if the electrolyte is molten sodium chloride
Cathode - sodium
Anode - chlorine
How does electrolysis of a solution (aq) work
At the cathode hydrogen is always discharged UNLESS COPPER, LEAD OR SILVER ions are present
At the anode oxygen is always discharged at UNLESS THERE IS A HALIDE ION (CHLORIDE, BROMIDE, IODIDE)
What is discharged at the cathode and anode for (aq) potassium bromide
Cathode - hydrogen
Anode - bromine
What are anions and cations
Anions are negative ions that lose electrons at the anode. This is oxidation
Cations are the positive ions that gain electrons at the cathode. This is reduction
Explain how one positive ion forms atoms at the negative electrode
The cation (positive ion) will go to the cathode there it will receive electrons they will bond causing the positive ion to be reduced as it is gaining electrons at the cathode and forming an atom