Reaction Summaries Flashcards
what is needed to go from an alkene to a poly(alkene)
high pressure catalyst
what is needed to go from an alkene to a dihalogenoalkane
Br2 Cl2 room temp
EAdd
what is needed to go from an alkene to a halogenoalkane
HBr HCl room temp
EAdd
what is needed to go from an alkene to an alcohol
Step 1: H2SO4
EAdd
Step 2 H2O warm hydrolysis
what is needed to go from an dihalogenoalkane to a diol
KOH aqueous heat under reflux
Nu Sub
what is needed to go from an alkane to a halogenoalkane
Br2 Cl2
UV light
Fr Sub
what is needed to go from a halogenoalkane to an alkene
KOH alcoholic
heat under reflux
Elimination
what is needed to go from a halogenoalkane to an alcohol
KOH aqueous
heat under reflux
NuSub
what is needed to go from a halogenoalkane to a nitrile
KCN in ethanol/water mixture
heat under reflux
NuSub
what is needed to go from a halogenoalkane to a primary amine
alcoholic NH3
heat under pressure
NuSub
what is needed to go from an alcohol to an alkene
conc H2SO4 or conc H3PO4
Elimination
dehydration
what is needed to go from an alcohol to an ester
carboxylic acid + H2SO4
heat
esterification
what is needed to go from an alcohol to a ketone
If secondary
Na2Cr2O7/H+
heat
oxidation
what is needed to go from an alcohol to an aldehyde
If Primary Na2Cr2O7/H+
heat and distill
partial ox
what is needed to go from a nitrile to a primary amine
LiAlH4 in ether reduction
what is needed to go from a primary amine to a secondary amine, tertiary amine, quaternary salt
haloalkane
NuSub
what is needed to go from a primary amine to a secondary amide
acyl chloride
room temp
Nu add/elim
what is needed to go from an aldehyde to an alcohol
NaBH4
Red Nu Add
what is needed to go from an aldehyde to a carboxylic acid
If primary Na2Cr2O7/H+
heat under reflux + excess oxidising agent
oxidation
what is needed to go from an aldehyde to a hydroxynitrile
NaCN + H2SO4
Nu Add
what is needed to go from a ketone to a hydroxynitrile
NaCN + H2SO4
Nu Add
what is needed to go from a ketone to an alcohol
NaBH4
Red Nu Add
what is needed to go from a carboxylic acid to an ester
alcohol + H2 SO4
heat
esterification
what is needed to go from an acyl chloride/acid anhydride to a carboxylic acid
H2O room temp
Nu add/elim
what is needed to go from an acyl chloride/acid anhydride to an ester
alcohol
room temp
Nu add/elim
what is needed to go from an acyl chloride/acid anhydride to a secondary amide
primary amine
room temp
Nu add/elim
what is needed to go from an acyl chloride/acid anhydride to a primary amide
NH3 room temp
Nu add/elim
conc nitric acid + conc sulphuric acid
electrophilic substitution
Sn and HCl
reduction
CH3Cl
Nu sub
CH3COCl
Nucleophilic add-el
acyl chloride in the presence of anhydrous aluminum chloride catalyst
Electrophilic substitution
NaCN + H2SO4
Nu Add
LiAlH4
reduction
NaBH4
Red Nu Add
CH3CO2H + H2SO4
heat
esterification