Reaction Rates Flashcards

1
Q

Rate of reaction

A

The change in concentration per unit time of any reacted or product

Rate is proportional to the slope of the line.

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2
Q

Average rate

A

The rate over the entire time of the reaction from start to finish

Volume/time= ar cm^3 per (unit time)

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3
Q

Instantaneous rate

A

The rate at a particular point in the reaction

Slope thang

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4
Q

Factors that affect rate of reaction

A

Concentration
/at higher conc. there are more particles. This means there can be more collisions with enough energy

Temperature
/at highe temperatures particles move faster. This means they are more likely to collide with enough energy.

Particle size
/smaller particles react faster as there are more particles free to collide

Catalyst
/a catalyst reduces the amount of avtivation energy needed.

Nature of reactants
/covalent - substances react slowly because chemical bonds need to be broken before new ones can be made.
/ionic - substances react quickly because there are no chemical bonds to be broken before new ones are made.

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5
Q

Collision Theory

A

For a chemical reaction to take place particles must collide with enough energy

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6
Q

Activation energy

A

The amount of energy needed for a reaction to take place

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7
Q

Catalyst

A

A substance that alters the rate of a chemical reaction but is not used up at the end of the reaction

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8
Q

Types of catalysts

A

Homogeneous
/same phase
//potassium iodide -> hydrogen peroxide (both liquid)

Heterogeneous
/reactants and catalysts are different phases
//catalytic oxidation of methanol by hot platinum

Autocatalysis
/when one of the products catalyses the reaction
//permanganate ions -> Fe^+2

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9
Q

Exothermic and endothermic

A

Has initial energy
Has lower energy

At the beginning (reactant)

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10
Q

Enzymes: biological catalysts

A

Catalase
/decomposes H2O2 in living things

Lysozyme
/catalyses the breakdown of cellwalls in bacteria

Hydrolases
/catalyses the breakdown of fats,proteins and carbs.

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11
Q

Catalytic converters

A

Help to reduce pollution from car exhausts

Platinum -> hydrocarbons
Palladium -> CO
Rhodium -> NO

NO2

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12
Q

Catalyst poisons

A

Lead

Pb in petrol is a catalytic poison and rapidly stops the catalyst from working

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