Reaction Rates Flashcards
What is the rate of a reaction?
The change in the concentration of a reaction or product in a given time.
—> How fast a reactant is used up/ how fast a product is formed.
Describe and explain how concentration of reactants changes over time.
D - The curve is the steepest at the start of the reaction when the rate is the greatest.
—> E - The reactants have the greatest concentration - the rate of reaction is the fastest.
D - The curve becomes less steep as the reaction proceeds.
—> E - The concentration of the reactants decreases - the rate of reaction slows down.
D - The curve becomes a straight line when the reaction is complete.
—> E - One of the reactants has been used up do the rate of reaction is 0.
Which factors affect the rate of reaction?
- Temperature
- Pressure
- Concentration
- Surface Area
- Catalysts
What is collision theory?
For a reaction to be successful, particles must collide in the correct orientation with energy which is greater than the activation energy.
How does concentration effect the reaction rate?
- If the concentration of the reactants increase, then the number of collisions increase.
- The proportion of molecules with energy greater than the activation energy remains the same.
- The frequency of successful collisions increases.
- Therefore, the rate of reaction increases.
(Inverse for decreasing conc.)
How does pressure effect the reaction rate?
- If the pressure increases, then the volume of the container has decreased., so, the number of collisions increases.
- The proportion of particles with energy greater that activation energy remains the same.
- The frequency of successful collisions increases.
- Therefore the rate of reaction increases.
(Inverse for decreasing pressure)
What are the two methods for following the progress of a reaction?
- Monitoring the removal of a reactant.
- Monitoring the formation of a product.
What are 2 ways of measuring the rate of reaction from a reaction which produces gases?
- Monitoring the volume of gas produced at regular time intervals using gas collection, ie. A gas syringe.
- Monitoring the loss of mass of reactants using a balance.
- REQUIRED PRACTICAL -
Describe how you could monitor the production of gas using gas collection.
- Set up a side-arm boiling tube connected to a gas syringe onto a clamp stand.
- Measure a known volume of a concentrated acid and add to the side-arm boiling tube.
- Place a piece of metal ribbon, of known mass, into the boiling tube and quickly put a stopper in place. Start the stop watch immediately.
- Record the volume of gas in the gas syringe every 10 seconds until the volume stays the same/ the reaction is over.
- Repeat the experiment with other concentrations of acid and represent your results on a graph of volume of gas produced against time.
Describe how you would monitor the loss of reactants using a balance.
- Add a carbonate and an acid to a conical flask placed on a balance.
- Record the initial mass of the flask and record the mass at regular time intervals.
- The reaction is complete when no more has is produced so, the mass no longer changes.
- Plot a graph of mass lost against time.