Reaction Rate Flashcards

1
Q

measure of the speed of any change that occurs within an interval of time

A

Rate

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2
Q

atoms, ions, and molecules can react to form products when they collide with one another, provided that the colliding particles have enough kinetic energy

A

collision theory

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3
Q

The minimum energy that colliding particles must have in order to react

A

activation energy

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4
Q

an unstable arrangement of atoms that forms momentarily at the peak of the activation-energy barrier

A

activated complex

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5
Q

The activated complex

A

transition state

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6
Q

substance that increases the rate of a chemical reaction without itself being consumed in the reaction

A

catalyst

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7
Q

exists in the same physical state as the reaction it catalyzes

A

homogeneous catalyst

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8
Q

exists in a physical state different than that of one of the reaction it catalyzes

A

heterogeneous catalyst

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9
Q

a substance that interferes with the action of a catalyst

A

inhibitor

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10
Q

an expression for the rate of a reaction in terms of the concentration of reactants

A

rate law

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11
Q

defines how the rate is affected by the concentration of that reactant

A

reaction order

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12
Q

numerical value that relates reaction rate and concentration of reactants at a given temperature
(also known as k)

A

specific rate constant

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13
Q

the reaction is directly proportional to the concentration of only one reactant

A

first-order reaction

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14
Q

rate is proportional to the square of the concentration of one reactant

A

second-order reaction

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15
Q

reaction in which reactants are converted to products in a single step

A

elementary reaction

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16
Q

consists of two or more elementary steps

A

complex reaction

17
Q

The series of elementary reactions or steps that take place during the course of a complex reaction.

A

reaction mechanism

18
Q

a product of one of the steps in the reaction mechanism

A

intermediate

19
Q

The slowest of the elementary steps in a complex reaction

A

rate-determining step

20
Q

is one in which the conversion of reactants to products and the conversion of products to reactants occur simultaneously

A

reversible reaction

21
Q

if a stress is applied to a system in dynamic equilibrium, the system changes in a way that relieves the stress

A

Le Châtelier’s principle

22
Q

The ratio of product concentrations at equilibrium, with each concentration raised to a power equal to the number of moles of that substance in the balanced chemical equation

A

equilibrium constant

23
Q

What four factors influence the rate of a chemical reaction?

A

Temperature, concentration, particle size, and the use of a catalyst

24
Q

What does it mean if a rate constant is large?

A

The products form quickly

25
Q

What does it mean if a rate constant is small?

A

The products form slowly

26
Q

What does an equilibrium constant greater than one mean?

A

Favors the products

27
Q

What does an equilibrium constant less than one mean?

A

Favors the reactants