Reaction Order Flashcards
Zero order
Increase the concentration of the reactant, but the rate doesn’t change, it’s zero order.
First order
If the reaction rate goes up by the same multiplicity as the concentration of the reactant, then it is first order.
Ex. Trial 1: 0.1M, 4 M/s = Trial 2: 0.4, 16 M/s
Second order
If the multiplicity of the reactant concentration squared = the multiplicity of the reaction rate, it’s second order.
Ex. Trial 1: 0.1M, 4.0M/s
Trial 2: 0.2 M, 16.0M/s
0.1*2 (the multiplicity) = 0.2
2^2 = 4 and 4.0 *4 = 16
If you’re multiplying the concentration by 2, you multiply the reaction by 4. Same for 3 and 9 and 4 and 16.
For the overall reaction order
Find the reaction order for A and B by looking at where it changes, then plug it in to the exponent of this equation: Rate = k[A]^x[B]^x
So if the order for “A” is 1 and the order for “B” is 2, the overall reaction order is: Rate= k[A]^1[B]^2