Reactants Flashcards by Hannah Andrews

Q

primary alcohol to carboxylic acid

A

H2SO4, Na2Cr2O7

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Q

primary alcohol to aldehyde

A

PCC

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Q

secondary alcohol to carboxylic acid

A

K2Cr2O7

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Q

secondary alcohol to ketone

A

H2SO4, Na2Cr2O7

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Q

secondary alcohol to aldehyde

A

not possible

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Q

alkyne to carboxylic acid or ketone

A

H2SO4, H2O

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Q

Ring closure

A

CH3CO3H

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Q

Triple bond to two carboxylic acids

A

O3 2. H2O, Zn

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Q

DiOl to aldehyde or ketone

A

HIO4

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Q

Cis elimination

A

H2, Lindlars catalyst

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Q

Trans elimination

A

Na, NH3

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Q

Trans ring opening

A

NaOH, H2O

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Q

Adds 2 Br on more substituted side of double bond

A

HBr

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Q

2 Br addition on less substitued side of double bond

A

HBr, peroxides

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Q

Markovnikov OH addition, and Br

A

Br2, H2O

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Q

Reduces Carboxylic Acid

A

H2, Pd

Q

Reduces Ketones

A

Zn(Hg), HCl, H2NNH2

Q

Aldehydes

A

BaHB4

Q

Reduces only C=O bonds

A

LiAlH4

Q

SN2 OH addition

A

NaOH

Q

SN2 SOCl2 addition

A

SOCl2, pyradine

Q

SN2 O2SCH3

A

ClO2SCH3, pyradine

Q

SN2 Br addition

A

PBr3

Q

SN1 SCH3

A

NaSCH3

Q

SN1 OCH3

A

Na, NH3, HOCH3

Q

SN1 X

A

NaX