Rates Of Reaction Flashcards
Explain reactants
A chemical reaction occurs when two or more substances (reactants) undergo a change whereby new products are created.
Reactants ——>Products
The reaction speed or rate can be measured as the ‘rate of formation of product’ or the ‘rate of disappearance of reactant’.
Examples of everyday chemical reactions.
Examples of some everyday chemical reactions are listed below
Burning of petrol in an engine fast Milk turning sour slow Making wine from grapes slower
What must happen before a chemical reaction?
Before a chemical reaction can happen, the molecules involved must collide and have enough energy to cause a reaction. The minimum energy required for a reaction to occur between molecules is called the activation energy.
How can you increase the rate of a chemical reaction ?
You can increase the rate of a chemical reaction by:
increasing the number of collisions, or
reducing the energy needed for the reaction to take place
ways of making the reaction surface area of a reactant larger.
The following methods are all ways of making the reaction surface area of a reactant larger. They also decrease the size of the reactant particles.
Dissolving a material in water
grinding the material into a fine powder
cutting the material into small pieces
spreading the material as a fine jet
What will happen when the effective reaction surface area is increased
The reaction rate will increase when the effective reaction surface area is increased (particle size is small).
A marble chip reacts fast in acid when it is crushed into a powder. A similar marble chip will react slowly if it is left as a solid lump.
Increasing the surface area of a reactant will increase the rate of a reaction.
How can temperature effect the rate of reaction
When a substance is heated its molecules have more energy and move faster.
The molecules of one reactant can collide more often with those of another reactant when the temperature is increased.
Increasing the temperature of reactants will increase the rate of reaction.
For example, iron filings will react faster in hot acid compared to cold acid.
How can concentration effect the rate of reaction
The greater the concentration, the more reactant molecules will be present per unit volume of the material.
There will be a greater chance for collisions to take place between reactant molecules so the reaction rate will increase.
If a gas is compressed into a smaller volume its pressure will increase and this will have the effect of increasing the concentration of the reactant gas molecules. Therefore, increasing pressure will increase the reaction rate.
A lump of marble chip will react faster in concentrated acid compared with dilute acid.
Increasing the concentration of reactants will increase the rate of reaction.
How a catalyst can effect the rate of reaction
A catalyst is a chemical which makes a reaction go faster but remains unchanged after the reaction. Catalysts are very useful substances in everyday life.
Manganese dioxide added to hydrogen peroxide will cause the peroxide to decompose to water and oxygen. The manganese dioxide is the catalyst in this reaction.
A catalyst takes part in a chemical reaction, but does not get used up and can be reused with more reactants. It is chemically the same at the end of the reaction.
Examples of every day catalysts
Nickel Making margarine from vegetable oils Vanadium pentoxide Manufacture of sulphuric acid Enzymes Various chemical changes in our bodies Iron Manufacture of ammonia Platinum Manufacture of nitric acid Catalysts in Cars Transition metals, for example platinum, are used as the catalysts in catalytic converters in a car exhaust. They speed up the reaction which converts harmful gases such as nitrogen oxides and carbon monoxides into less harmful gases like nitrogen and carbon dioxide
How can changing the variables in an experiment effect it
In any experiment investigating the effects of changing one variable, for example the concentration of reactants, all other variables in the investigation must be kept the same, for example temperature or the volume of reactants.
If you change two variables at the same time, you will not know which on
Explain the reaction rate graph
The rate of a chemical reaction may be measured by plotting a graph of the mass of a product produced with time.