rates of reaction Flashcards
rate of reaction
the change in concentration of reactant or product with respect to time
order of reaction
the power to which the concentration of a reactant is raised to in the rate equation
overall order of reaction
the sum of the powers to which the concentration terms are raised to in the rate equation
rate constant
the proportionality constant that links rate of reaction to concentration in the rate equation
rate determining step
the slowest step in the mechanism of a reaction
deduce simple rate equation
rate = conc/time
first order
is a is doubled rate is doubled
second order
if a is doubled rate is quadrupled (ie square)
third order
if a is doubled rate is x8 (ie cubed)
factors effecting rate
temperature (faster more successful collision greater kinetic energy)
pressure (more successful collisions as particles are closer together in a given period of time)
concentration (more reacting particles present in the same volume)
catalyst (provides an alternative reaction pathway of lower activation energy)