Rates of Reaction Flashcards

1
Q

Explain how chemical reactions occur

A
  • For chemical reactions to occur, reactant particles must collide with each other with enough energy to react
  • The minimum amount of energy required for a reaction to occur is called the activation energy
  • During successful collisions, this energy helps to break bonds, so that atoms can be rearranged to make new substances (the products of the reaction)
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2
Q

What are reactions that release energy called?

A

Exothermic Changes

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3
Q

What are reactions that take in energy to occur called?

A

Endothermic Changes
- These will not keep going unless energy is continuously supplied

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4
Q

When are reaction rates generally increased? - why?

A
  • When energy increases
  • When frequency increases (number of collisions in a certain amount of time)
    When the energy is increased, more successful collisions will occur if more particles have the activation energy required
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5
Q

What affect does concentration have on reaction rate?

A
  • Increasing the concentration of solutions increases the rate of reaction
    There are more reacting particles in the same volume, so collisions occur more often
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6
Q

What affect does surface area have on reaction rate?

A
  • Increasing the surface area to volume ratio increases the rate of reaction
    There is more surface for collisions to occur on, so collisions occur more often
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7
Q

What affect does pressure of gases have on reaction rate?

A
  • Increasing the pressure of gases increases the rate of reaction
    The reactant particles are squeezed closer together, so collisions occur more often
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8
Q

What affect does temperature have on reaction rate?

A
  • Increasing the temperature increases the rate of reaction
    Reactant particles speed up and have more energy. Therefore, they collide more often and more particles have enough energy for a successful collision when they collide
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9
Q

What are catalysts?

A

Catalysts are substances that speed up chemical reactions without being permanently changed themselves, in mass or chemically, at the end of the reaction, and without altering the products

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10
Q

Explain how catalysts increase the rate of reaction, in terms of activation energy

A

It provides an alternative reaction route that requires less energy to start the reaction, so more reactant molecules have enough activation energy so more collisions are successful and thus the rate of reaction increases

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11
Q

What are enzymes?

A

Biological catalysts used in the production of alcoholic drinks

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12
Q

Explain the role of enzymes in the production of alcoholic drinks

A

Enzymes found in yeast catalyse the reaction in which glucose is converted into ethanol and carbon dioxide

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13
Q

Explain the role of catalysts in car exhausts

A
  • In catalytic converters in car exhausts, the catalysts are platinum and palladium
  • Their presence lowers the activation energy needed to convert harmful gases into harmless gases
  • The metals used are expensive, but don’t need to be replaced as they are not used up
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14
Q

Why are reaction rates at the start the fastest? (concentration graph)

A

The concentration of reactants is the highest

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15
Q

How can we investigate reaction rates?

A

By measuring the amount of reactants or products changes with time
- Changes in the concentration
- Changes in the mass
- Changes in the volume

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16
Q

How can we follow the rate of reaction between sulfuric acid and magnesium? (magnesium ribbon vs granules)

A
  • Measure volume of hydrogen gas produced using a gas syringe
  • Magnesium granules react faster as they have a higher surface area to volume ratio
17
Q

How can we follow the rate of reaction between marble (calcium carbonate) and hydrochloric acid?

A
  • Measure the change in mass before and after reaction
  • Mass decreases as carbon dioxide gas escapes from the conical flask
18
Q

Core Practical: Investigating reaction rates - surface area

A
  • 40cm cubed dilute hydrochloric acid in a conical flask
  • Add 5g small marble chips to the flask
  • Immediately add a bung connected to a delivery tube which goes into a water trough with an upside down measuring cylinder to the flask
  • Record the total volume of gas produced every 30 seconds
  • Repeat the experiment with 5g of larger marble chips
19
Q

Core Practical: Investigating reaction rates - concentration

A
  • 10cm cubed thiosulfate solution into a conical flask
  • Place conical flask onto a printed cross
  • Add 10cm cubed of hydrochloric acid
  • Swirl solution and start a stop watch
  • Look down from the top and stop the clock when you can no longer see the cross
  • Repeat experiment with lower concentrations of sodium thiosulfate solution

You could investigate this with temperature by placing solution in water bath and repeat at different temperatures

20
Q

How do you calculate the overall rate of reaction?

A

Quantity of reactants used/time taken
OR
Quantity of products formed/time taken