Rate Of Reaction Flashcards

1
Q

How can we use a precipitates to determine the rate of reaction?

A

This is when the product of a reaction is a precipitate which clouds the solution

We can observe a mark through a clear solution and measure how long it takes for the mark to disappear

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2
Q

Give an example experiment of a precipitate reaction

A

React the clear solutions of sodium thiosulfate and hydrochloric acid together. This forms a yellow precipitate of sulphur

The experiment involves watching a black mark disappear through cloudy sulphur and timing how long it takes to go with a stopwatch

The reaction can be repeated for solutions at different temps( using a water bath to heat both solutions to the desired temperature)

Control: volume and concentration of solutions

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3
Q

What is the rate of reaction?

A

How fast reactants turn into products

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4
Q

What does the rate of reaction depend on?

A

Temperature
Concentration
Surface area
Catalyst

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5
Q

Why does temperature increase the rate of reaction?

A

Particles gain energy energy and move more quickly
Particles collide more often
So greater chance of successful collisions

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6
Q

Why does an increased concentration in solutions increase the rate of reaction?

A
More particles( of the reactants) are moving around the same volume of solution. So the reactant particles are more 'crowded' together 
Therefore the reactant particles  are likely to collide more frequently.

( same with gas only now there are more gas particles in a given space etc….)

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7
Q

Why does a larger surface area increase the rate of reaction?

A

If the surface in question was a solid, breaking it into pieces increases the total surface area
So particles around it( in the solution) will have a greater area to work on
Therefore there will be more frequent collisions as there are more particles( of the surface) exposed to attack.

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8
Q

What is the activation energy?

A

The smallest amount of energy that particles must have before they react.

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9
Q

What are catalysts?

A

Substances that increase the speed the rate of reaction
Without being chemically changed or used up in the reaction
Only need a tiny bit to catalyse huge reactions

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10
Q

Why are catalysts usually in the form of pellets?

A

Give them the biggest possible surface area.

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11
Q

How do catalysts work?

A

A catalyst increases the number of SUCCESSFUL collisions
It works by giving the reacting particles a surface to stick to where they can bump in to each other
It reduces the activation energy needed by particles before they react

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12
Q

Why are catalysts useful in industry?

A

Catalysts increase the rate of reaction which saves a lot of energy and consequently money because the plant doesn’t have to operate as long to produce the same amount of product

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13
Q

What are the Advantages and disadvantages of catalysts

A

Can allow reactions to work at lower temperature
So less energy used
So conserves fossil fuels and saves money

Disadvantages:

They are very expensive to buy and often have to be removed from the product of the reaction and cleaned from it

Different reactions use different catalysts, so if businesses make more than one product they’ll need multiple catalysts

Poisoned by impurities and easily stop working.

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14
Q

What are Exothermic reactions?

A

Exothermic reactions are reactions that transfer energy to the surroundings
They are indicated by a temperature rise.

Some examples see combustion and neutralisation reactions( acid and alkali)

Many oxidation reactions are exothermic like like respiration

Used in hand warmers( oxidation of iron) and self heating cans( calcium oxide and water to make calcium hydroxide)

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15
Q

What are endothermic reactions?

A

Endothermic reactions are reactions that take in energy from the surroundings
Indicated by a fall in temperature
Examples are thermal decomposition reactions
E.g calcium carbonate

They are also used in a more domestic setting, e.g sport injury packs( take heat in and become very cold)

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16
Q

Describe an experiment showing the rate of reaction with the effect of catalyst ( decomposition of hydrogen peroxide)

A

2 H2O2 = 2 H20 +O2

This is normally a slow reaction but it can be sped up with manganese oxide.

Oxygen is given off and you can time with a stop watch how much gas is given off in one minute.

The volume of oxygen gas can be measured with a gas syringe( reaction shouldn’t be too vigorous or you’ll blow plunger out the end of the syringe)

17
Q

Describe an experiment measuring the effect of concentration using the mass balance method( magnesium and HCL)

A

React the magnesium metal with the HCL acid in a beaker and place on mass balance
Hydrogen gas should be released should be released into air
Take readings of mass at regular time intervals
Put results in a results table and work out mass lost from each reading.

Repeat for different concentration but same mass of magnesium and volume of HCL