Rate Of Reaction Flashcards

1
Q

What is the rate of the reaction?

A

The speed of a reaction

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2
Q

Name examples of chemical reactions and if they are slow or fast

A

Rusting - slow reaction
Explosion- fast
Weathering- slow
Sodium in water- fast
Rotting fruit - slow

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3
Q

Name 5 ways to speed up a reaction

A

Increase temperature
Increase concentration of a liquid
Increase pressure of gases
Use a catalyst
Increase surface area of solid

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4
Q

Describe collision theory/ how you know when a reaction happens

A

If a reaction happens:
-Particles are constantly moving
-for the collision to be successful the particles must have the right amount of activation energy- The minimum amount of energy required for an effective collision
- more frequent collisions
- then new substances are formed

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5
Q

What is the equation for calculating rate of reaction?

A

Amount of reactant used or amount of product made/ time taken

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6
Q

Describe method for required practical- concentration and rate

A
  • make a cross with a board one on piece of paper
  • measure 50ml of sodium thiosulfate (40g/dm3) using large measuring cylinder
  • put sodium thiosulfate into conical flask
  • put conical flask on top of cross
  • measure 10ml of hydrochloric acid using small measuring cylinder
  • add hydrochloric acid to conical flask and start the stop watch at same time and swirl
  • stop stopwatch when cross has completely disappeared
  • repeat with different concentrations- 32g/dm3, 24g/dm3, 16g/dm3, 8g/dm3
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7
Q

Describe method for required practical- concentration and rate

A
  • make a cross with a board one on piece of paper
  • measure 50ml of sodium thiosulfate (40g/dm3) using large measuring cylinder
  • put sodium thiosulfate into conical flask
  • put conical flask on top of cross
  • measure 10ml of hydrochloric acid using small measuring cylinder
  • add hydrochloric acid to conical flask and start the stop watch at same time and swirl
  • stop stopwatch when cross has completely disappeared
  • repeat with different concentrations- 32g/dm3, 24g/dm3, 16g/dm3, 8g/dm3
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8
Q

And symbol equation for the required practical- concentration and rate when sodium thiosulfate reacts with hydrochloric acid

A

Sodium thiosulfate + hydrochloric acid -> sodium chloride + sulfuric acid dioxide + sulfur + water

Na2S2O3 (aq) + 2HCl (aq) -> 2NaCl (aq) + SO2 (g) + S (s) + H2O (l)

Sulfur is a white solid so it turns the solution cloudy

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9
Q

What are the variables for required practical concentration and rate?

A

Independent- concentration of sodium thiosulfate
Dependent- time taken for cross to disappear
Control - volume of sodium thiosulfate
Volume of hydrochloric acid
Same person look for cross disappearing
Concentration of hydrochloric acid

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10
Q

Write risk assessment for required practical- concentration and rate

A

Risk - hydrochloric acid
Hazard - irritate skin
Controlling risk- wash off skin, wear goggles

Risk- glassware
Hazard- cuts
Controlling risk- tell teacher if broken

Risk- sulfur dioxide
Hazard- irritates asthma
Controlling risk - open windows, keep distance

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11
Q

What graph do you plot for the required practical ?

A

Line graph as the independent and dependent variable are continuous

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12
Q

Describe method for required practical- temperature and rate

A
  • measure 50cm3 of 1.0M hydrochloric acid using a measuring cylinder. Pour the acid into the 100cm3 conical flask
  • fit the bung and delivery tube to the top of the flask
  • half fill the trough or bowl with water
  • fill other measuring cylinder with water. Make sure it stays filled with water when you invert it into water trough and delivery tube is positioned correctly
  • add 1.3cm strip of magnesium ribbon to flask, put bung back as quickly as possible and start stop watch
  • record volume of hydrogen gas given off at suitable intervals, continue timing until volume of gas doesn’t change
  • repeat steps 1-6 using hydrochloric acid at 40 degrees
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13
Q

Write risk assessment for required practical - temperature and rate

A

Risk- magnesium
Hazard- flammable
Controlling risk- no use if Bunsen burner in experiment

Risk- hydrogen gas
Hazard- flammable
Controlling risk- no use of Bunsen burner

Risk- glassware
Hazard- cuts
Controlling risk- tell teacher

Risk- hydrochloric acid
Hazard- irritates skin
Controlling risk- rinse off
Wear goggles

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14
Q

How does increasing temperature effect rate of reaction

A
  • increasing temp causes rate of reaction to increase because particles have more kinetic energy and move faster so there are more frequent collisions
    -also more particles have the activation energy
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15
Q

How does increasing the concentration affect the rate of reaction?

A

Increasing concentration increases rate of reaction because there are more particles so this causes more frequent collisions
(Increasing pressure is the same as increasing concentration)

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16
Q

How does increasing surface area effect the rate of reaction ?

A

Increasing the surface area, increases the rate of reaction
To increase the surface area u need to make the substance smaller (use powdered)
This causes more frequent collisions

17
Q

What are catalysts?

A

Speed up a reaction but aren’t used up
Only small amounts are needed
Catalysts are specific to a reaction
They aren’t included in the chemical equation

18
Q

How do catalysts affect the rate of reaction?

A

Increase the rate of reaction by providing a different/ alternating pathway for the reaction that has a lower activation energy

19
Q

Write steps for working out the rate (gradient) of a straight line

A

1 make a triangle using your line
2 workout change in y axis
3 workout change in x axis
4 workout rate = change in y /change in x

20
Q

Write steps for working out rate of curved line

A

1 fine the plot on the curve (in the question)
2 draw a straight line that touches the point , and make a triangle
3 workout change in y and x axis
4 workout gradient = change in y / change in x

21
Q

What are reversible reactions?

A

A reaction that goes both forwards and backwards
The reactants change into products and as soon as some products are made they react to form the reactants

22
Q

Give an example of a reversible reaction and state the forwards and backwards reaction

A

Heating copper sulfate
Forward= exothermic
Backward = endothermic

23
Q

Write an equation for a reversible reaction

A

Hydrated copper sulfate (blue) reversible reaction symbol Anhydrous copper sulfate (white) + water

24
Q

When is equilibrium reached?

A

When the rate of forwards reaction is the same as the rate of backwards reaction in a closed system

25
Q

What does a closed system do?

A

Stops any reactants or products escaping

26
Q

What conditions when Changed, changed the equilibrium?

A

Concentration
Pressure
Temperature

27
Q

Explain what happens to the yield when u increase the concentration

A

1) write rule- if u increase the concentration of the reactant equilibrium will move to the side of the products
2) write which direction equilibrium will move- will move forwards
3) write what happens to the amount of product made - more product is made

28
Q

What happens to the yield when you increase the pressure?

A

1) workout number of molecules in each side
2) write the rule- if we increase the pressure equilibrium moves to the side with less molecules
3) write which direction the equilibrium will move
4) write what happens to the amount of product made

29
Q

What happens to the yield when we increase the temperature?

A

1) write on the equation the endothermic and exothermic direction
2) write the rule- when u increase the temp the equilibrium moves in the endothermic direction
3) write which direction the equilibrium will move
4) write what happens to the amount of product made