Rate of reaction Flashcards

1
Q

What is the rate of a reaction

A

How quickly reactants are used up or products are formed

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2
Q

What are the 2 equations for the mean rate of reaction

A

Mean rate of reaction= quantity of reactant used/time taken

Mean rate of reaction=quantity of product formed/time taken

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3
Q

How would you measure volume of gas produces and what is the equation

A

connect the reaction mixture to a gas syringe
Rate= Volume of gas produced/time taken

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4
Q

What are the 3 units for rates of reaction

A

Mass- g/s
Volume- cm/s
Moles- Mol/s

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5
Q

What do steep and shallow gradients mean when calculating rates from graphs

A

steep gradient- high rate of reaction
Shallow reaction- low rate of reaction

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6
Q

How do you calculate the rate of reaction from a graph

A

draw tangents to curves and Calculate​ ​the​ ​gradient​ ​of​ ​the​tangent​
measure​ ​of​ ​rate​ ​of​ ​reaction​ ​at​ ​a​ ​specific​ ​time (change in y over change in x)

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7
Q

What is collision theory

A

chemical reactions can occur only when reacting particles
collide with each other and with sufficient energy

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8
Q

What is activation energy

A

The minimum amount of energy that particles must have to
react

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9
Q

How does increasing surface area of solids increase rate of reaction

A

More reactant particles are exposed leading to more frequent collisions

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10
Q

How does increasing the pressure increase rate of reaction

A

Less space between particles means more frequent collisions

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11
Q

How does increasing the concentration increase the rate of reaction

A

more reactant particles in mixture , so more frequent collisions

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12
Q

How does increasing temperature increase rate of reaction

A

1) particles move faster so more frequent collisions
2)particles have more kinetic energy, so collisions more energetic

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13
Q

What are catalysts

A

substances that speed up chemical reactions without being changed or used up during the reaction

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14
Q

What effect do catalysts have on activation energy

A

Catalysts provide a different pathway for a chemical reaction that has a lower activation
energy.

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15
Q

What effect does lowering activation energy have on particles

A

increases the proportion of particles with energy to react.
More particles will collide with enough energy, so more collisions result in a reaction

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16
Q

What is a reversible reaction and what is the symbol

A

the products of the reaction can react to produce the original reactants
A+B⇌C+D

17
Q

If a reaction is exothermic one way what will be the reaction the other way

A

endothermic

18
Q

Is the same or different amount of energy transferred each way

A

Same

19
Q

What is a closed system

A

Where no reactants or products can escape

20
Q

What is dynamic equilibrium

A

When a reversible reaction occurs in a closed system,
dynamic equilibrium is reached
when the reactions occur at exactly the same rate in each direction

21
Q

What is the impact of dynamic equilibrium on the amount of reactants and products

A

the overall amount of products and reactants are constant but not necessarily equal

22
Q

What are the conditions and how can you change them

A

External environment of a reaction. you can change them by:
Changing the concentration of one of the substances
Changing the temperature of the entire reaction vessel
Changing the pressure inside the vessel

23
Q

What is Le Chatelier’s principle

A

If a reaction at equilibrium is subjected to a change any of the conditions, the position of equilibrium will move to
counteract the change.

24
Q

What is the effect of increasing the concentration of reactants at dynamic equilibrium

A

Favors forward reaction

position​ ​of​ ​equilibrium​ ​shifts
towards​ ​products​ ​so​ ​more​ ​product​ ​is​ ​produced​ ​until​ ​equilibrium​ ​is​ ​reached
again

25
Q

What is the effect of increasing the concentration of products at dynamic equilibrium

A

Favours backward reaction

position​ ​of​ ​equilibrium​ ​shifts​ ​towards reactants​ ​so​ ​more​ ​reactant​ ​is​ ​produced​ ​until​ ​equilibrium​ ​is​ ​reached​ ​again

26
Q

What is the effect of increasing the temperature of the surroundings

A

equilibrium​ ​moves​ ​in​ ​the​ ​direction​ ​of​ ​the
endothermic​ ​reaction​

27
Q

What is the effect of decreasing the temperature of the surroundings

A

equilibrium​ ​moves​ ​in​ ​the​ ​direction​ ​of​ ​the
exothermic​ ​reaction

28
Q

What is the effect of changing pressure in a gaseous reaction

A

an​ ​increase​ ​in​ ​pressure​ ​will​ ​favour​ ​the​ ​reaction​ ​that
produces​ ​the​ ​least​ ​number​ ​of​ ​molecules​ ​as​ ​shown​ ​by​ ​the​ ​symbol​ ​equation​ ​for
that​ ​reaction

29
Q

What is the effect of increasing pressure

A

equilibrium​ ​shifts​ ​to​ ​side​ ​of​ ​equation​ ​with​ ​fewer​ ​moles
of​ ​gas

30
Q

What is the effect of decreasing pressure

A

equilibrium​ ​shifts​ ​to​ ​side​ ​of​ ​equation​ ​with​ ​more​ ​moles
of​ ​gas