Rate Of Equation Flashcards
Define reaction rate
Increase in concentration of products per unit time or the decrease in concentration of reactants per unit time
How to determine the unit for rate?
(mol dm-3) ^1-n s-1
n= overall equation
Define rate equation/rate law
Equation that describes the mathematical relationship between the rate of reaction and [rxts]
Define order of reaction
In an experimentally determined rate equation,
rate=k[A]^x
where X= order of reaction wrt A
How zero order of reaction changes when [rxt] changes?
No change
-> rate is independently of concentration
How first order of reaction changes when [rxt] changes?
•rate is directly proportionate to [A]
Eg: if rate x4, [A] x4
•it will have a constant half-life
-> t0.5=ln2/k
How second order of reaction changes when [rxt] changes?
•rate is propor. to [A]^2
Define half-life
Time taken for the concentration of a reactant to fall half its initial value. It is only constant for a first order of reaction
Define rate constant
In an experimentally determined rate equation,
rate= k[A]^x
where k= rate constant