Rate Of Equation Flashcards

1
Q

Define reaction rate

A

Increase in concentration of products per unit time or the decrease in concentration of reactants per unit time

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2
Q

How to determine the unit for rate?

A

(mol dm-3) ^1-n s-1

n= overall equation

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3
Q

Define rate equation/rate law

A

Equation that describes the mathematical relationship between the rate of reaction and [rxts]

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4
Q

Define order of reaction

A

In an experimentally determined rate equation,

rate=k[A]^x
where X= order of reaction wrt A

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5
Q

How zero order of reaction changes when [rxt] changes?

A

No change

-> rate is independently of concentration

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6
Q

How first order of reaction changes when [rxt] changes?

A

•rate is directly proportionate to [A]
Eg: if rate x4, [A] x4

•it will have a constant half-life
-> t0.5=ln2/k

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7
Q

How second order of reaction changes when [rxt] changes?

A

•rate is propor. to [A]^2

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8
Q

Define half-life

A

Time taken for the concentration of a reactant to fall half its initial value. It is only constant for a first order of reaction

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9
Q

Define rate constant

A

In an experimentally determined rate equation,

rate= k[A]^x
where k= rate constant

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