Rate expression Flashcards

1
Q

Rate expression

A

rate=k[A][B]2

k= rate constant

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2
Q

Zero order reactant

A

Change in its concentration does not change rate of reaction;not included in rate expression

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3
Q

Example of zero order reactant

A

Solids(e.g. magnesium)
Pure liquids

We cannot change the concentrations of these

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4
Q

First order reactant

A

Directly proportional i.e.
Doubling its concentration doubles rate of reaction

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5
Q

Second order reactant

A

Increasing concentration by factor x increases rate by factor x2

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6
Q

Which catalysts can be included in the rate expression?

A

Homogenous catalysts (not the solid ones)

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7
Q

How to calculate overall order

A

Add up the orders of the individual reactants

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8
Q

What does it mean if rate=k?

A

O order reaction. None of the reactants affect the rate.

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9
Q

Units of k for reaction of overall order 0

A

mol dm-3 s-1

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10
Q

Units of k for reaction of overall order 1

A

sec-1

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11
Q

Units of k for reaction of overall order 2

A

mol-1 dm3 s-1

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12
Q

Units of k for reaction of overall order 3

A

mol-2 dm6 s-1

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