Rate Equations Flashcards
What is the rate equation?
Rate = k[A]m[B]n
What do m and n tell you?
The orders of A and B, respectively.
What is k, and in what case is it affected?
k is the rate constant which remains constant for a certain reaction.
It is affected when temperature is changed.
How is the total order calculated?
By adding the individual orders together.
What is the definition for the Reaction Rate?
The reaction rate is the change in the amount of reactants or products per unit time.
How can you figure out the reaction rate from a concentration-time graph?
You measure the gradient ((y2-y1)/(x2-x1)).
How can you use a concentration-time graph to deduce the order of reaction (via rate-conc.)
By plotting a rate-concentration graph by calculating the rate from several points on a concentration-time graph, then drawing a line of best fit through them.
0 order = horizontal line.
1st order = straight line w/ gradient.
2nd order = parabolic curve.
If you increase a reactant’s concentration by x and the rate *?*, the order w.r.t that reactant is 0.
stays the same.
If you increase a reactant’s concentration by x and the rate *?*, the order w.r.t that reactant is 1.
increases by x.
If you increase a reactant’s concentration by x and the rate *?*, the order w.r.t that reactant is 2.
increases by x2.
What is the definition for Half-Life?
The half life (t1/2) of a reaction is the time taken for half of the reactant to react.