Random revision - Unit 1 Flashcards

1
Q

What is the activation energy?

A

The minimum energy required by colliding molecules for a reaction to occur

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2
Q

Why is it essential that chemists can predict the quantity of heat taken in or given out in an industrial process?

A
  1. Endothermic reactions require heating which results in high energy costs.
  2. Runaway reactions such as those causing the disasters in Bhopal and Seveso occur when the rate at which a chemical reaction releases energy exceeds the capabilities of the plant to remove heat.
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3
Q

What is temperature?

A

A measure of the average kinetic energy of the particles in a chemical

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4
Q

Describe the reactivity of group 7

A

They are reactive. The reactivity decreases down a group.

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5
Q

What happens to metallic characteristics across a period

A

They decrease

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6
Q

What is an exception to ‘compounds formed between non metals only, are covalent

A

Some metals form covalent compounds, e.g. SnI4 and TiCl4

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7
Q

What is an exception to “compounds formed between a metal and non mental are ionic”

A

Acids are also ionic, HCl, H2SO4, HNO3

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8
Q

What are Intramolecular forces

A

The forces that hole atoms together to form a molecule - Polar/Pure covalent bonds

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9
Q

WhT are intermolecular forces

A

The forces of attraction between molecules - Van see Waals forces

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10
Q

How do LDFs arise

A

Temporary uneven distribution of electrons within atoms and molecules

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11
Q

The higher the mpt/bpt, the ______ the intermolecular forces

A

Stronger

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12
Q

Why does ice float on water

A

Ice is less dense because hydrogen bonding between water molecules give ice an open structure. (Molecules of H2O in Ice are further apart) The density of i a is lower than water unlike other chemicals where Solid is more dense than Liquid.

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13
Q

What is viscosity

A

Thickness

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14
Q

Why does ionisation energy increase across a period?

A

The nuclear charge increases as you go across a period. This means that the outer electrons are more strongly attracted to the positive nucleus and are pulled in tighter, requiring more energy to remove them.

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15
Q

where do LDFs arise

A

between all atoms and molecules

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16
Q

What is an activated complex

A

As the reaction proceeds from reactants to products, an unstable intermediate stage is reached at the top of the activation barrier at which a highly energetic species called an activated complex is called

17
Q

Describe covalent molecules

A

Covalent molecules or compounds have a definite number of atoms bonded tigether

18
Q

Describe covalent networks

A

Covalent network elements or compounds have a vast but indefinite number or atoms bonded together

19
Q

Explain the change in ionisation energies across a period

A

As you go across a period the positive charge in the nucleus increases making the atoms smaller. The outer electrons are closer to the nucleus so more strongly attracted. The outer electron is more difficult to remove so the ionisation energy increases.

20
Q

Explain the change in ionisation energies down a group

A

As you go down a group the atoms are bigger as there is another shell of electrons. The outer electrons are further from the nucleus and are also shielded from the full effect of the nucleus by the inner electrons. The outer electron is easier to remove so the ionisation energy increases.

21
Q

Explain the effect of the electronegativity on electrons in a covalent bond

A

The higher the electronegativity the stronger the attraction of the atom for the shared electrons in a covalent bond.

22
Q

What is electronegativity

A

Electronegativity is a chemical property that describes the tendency of an atom or a functional group to attract electrons toward itself