Random Chemistry 🧪 Flashcards

1
Q

Formation of electrophile during nitration of benzene:

A

2H₂SO₄ + HNO₃ –> 2HSO₄- + H₃O+ + NO₂+

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2
Q

Reagent for the hydrolysis of a peptide bond

A

CONCENTRATED NaOH or CONCENTRATED HCl

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3
Q

How would you name a compound containing two aldehyde groups?

A

alkanedial

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4
Q

How would you name a compound containing two ketone groups?

A

alkane - x,y - dione

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5
Q

how would you name a compound containing a ketone group and a carboxylic acid / aldehyde?

A

y-oxoalkanoic acid
OR
y-oxoalkanal

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6
Q

how would you maximise the amount of primary amine formed during nucleophilic substitution?

A

use an excess of ammonia

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7
Q

how would you maximise the formation of a quaternary ammonium salt during nucleophilic substitution?

A

use an excess of halogenoalkane

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8
Q

define periodicity

A

repeating trends

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9
Q

suggest a reagent for the conversion of [Fe(H₂O)₆]³+ to [Fe(H₂O)₆]²+

A

excess Zn

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10
Q

state the main observation produced when NaBr is added to sulfuric acid

A

orange fumes

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11
Q

how many lone pairs does oxygen have

A

2

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12
Q

equation for formation of acid rain

A

SO2 + H2O –> H2SO3

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13
Q

sugar in DNA

A

2-deoxyribose

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14
Q

suggest why condensation polymers are biodegradable whereas addition polymers aren’t (2 marks)

A
  • As there is a polar C=O group

- Therefore, it can be attacked by nucleophiles (leading to breakdown)

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15
Q

how do hydrogen bonds form within proteins (3 marks)

A
  • nitrogen + oxygen are very electronegative
  • so C=O and N-H are polar
  • so lone pair on oxygen atom attracted strongly towards the partially positive hydrogen
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