Quiz December 7th Flashcards

1
Q

What does colligative mean?

A

Depending on the amount of substance, not the identity

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2
Q

What are some colligative properties? (4)

A

Osmotic pressure, freezing point lowering, boiling point elevation, vapor pressure lowering

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3
Q

What is vapor pressure?

A

The pressure exerted by a vapor

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4
Q

What does volatile mean?

A

Can evaporate easily, low boiling point

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5
Q

What does nonvolatile mean?

A

Cannot evaporate easily

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6
Q

Vapor pressure is lowered when ________ substance is added

A

nonvolatile

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7
Q

vapor pressure over a liquid is a result of

A

dynamic equilibrium

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8
Q

What is dynamic equilibrium?

A

When the rate at which the vapor molecules return to liquid form, is equal to rate at which liquid molecules evaporate

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9
Q

Vapor pressure over the solution with a non-volatile solute, is always _______ than the vapor pressure above the pure solvent

A

less

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10
Q

What does Raoult’s law state?

A

the vapor pressure of a solution is proportional to the mole fraction of the solvent

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11
Q

What does Dalton’s law state?

A

The total pressure is equal to the partial pressure of each of the gases in the mixture

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12
Q

It is _______ to freeze and to boil solutions with nonvolatile solutes

A

more difficult, harder

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13
Q

If a solution has a nonvolatile solute added, the vapor pressure _________

A

lowers

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14
Q

In osmosis, the solvent…

A

goes from an area of higher solvent concentration (lower solute concentration) to an area of lower solvent concentration (higher solute concentration)

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15
Q

hydrostatic pressure is equal to ______ ______

A

osmotic pressure

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16
Q

What is osmolarity?

A

the sum of molarity of independent particles

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17
Q

If the osmolarity of 2 substances is equal,

A

they have the same vapor pressure, boiling point, freezing point, and osmotic pressure

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18
Q

What is a non-electrolyte?

A

A substance that dissolves in molecular form

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19
Q

What is an electrolyte?

A

A substance that dissociates in a solution (produces ions)

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20
Q

Solution of _________, show greater differences than solutions of ___________

A

Electrolytes, non-electrolytes

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21
Q

If the solute concentration outside of the cell is greater than inside the cells it is ________ and water moves _______ the cell. _______ occurs

A

hypertonic, outside. Crenation

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22
Q

If the solute concentration outside of the cell is LESS than inside of the cell, it is _________. Water moves ________ the cell. ________ occurs.

A

Hypotonic. Into. Hemolysis

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23
Q

What is hemolysis?

A

destruction of red blood cells

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24
Q

What is crenation?

A

cell shrinking

25
What is reverse osmosis?
applying pressure to the solution, so the solvent moves from the more concentrated side to the other side
26
What is reverse osmosis often used for?
To get pure water from salt water
27
What is a colloid?
stable system of two phases, with one dispersed in the other; cannot be easily separated
28
What are some examples of colloids?
Marshmallow (solid foam), aerosol (fog), whipped cream (foam)
29
What is the Tyndall effect?
Colloidal suspensions can scatter rays of light
30
Example of a colloid in a biological system
Sodium stearate (emulsifies fat in aqueous solutions), soap (non-biological)
31
What is a reaction rate?
The speed of a chemical reaction
32
_________ changes in chemical reactions.
Concentrations
33
Reaction rate is equal to
the change of molar concentration over time
34
What is collision theory?
With enough energy and the right orientation, molecules can form products when they collide
35
What makes a collision ineffective?
Not enough energy
36
Activation energy is
the minimum required energy to make a reaction occur
37
If there is low activation energy, the reaction is ______
fast
38
If there is high activation energy, the reaction is ______
slow
39
What are 5 factors that effect reaction rates?
Temperature, chemical identity, particle size, concentration, catalysts
40
How does the particle size influence a reaction rate?
Depending on the size of the particles, there is more area for particles to react in more places and more frequently
41
How does temperature effect reaction rates?
In higher temperatures, reactions happen more quickly... particles move faster
42
How do catalysts effect reaction rates?
Catalysts make reactions follow a different pathway so less activation energy is needed
43
Catalysts are ___ consumed in the reaction
not
44
Enzymes are special __________
Biocatalysts
45
Enzymes are catalysts, but.....
Not all catalysts are enzymes
46
What is a special/elementary reaction?
A reaction that occurs in one step (uncommon)
47
What is the order of reactions?
the number of particles that should collide at the same time and place to react with eachother
48
concept of equilibrium is also called a
reversible reaction
49
Equilibrium is when
a reaction and it's reverse reaction happen at the same rate
50
once equilibrium is reached, the amount of products and reactants ______ _________
remain constant
51
In the equilibrium constant,
K has no unit
52
What is stoichiometry?
balancing
53
if K > 1
There is more product at equilibrium
54
if K
There is more reactant at equilibrium
55
Adding heats shifts the equilibrium in the ______ direction
Endothermic
56
What are factors that effect equilibrium?
The Haber process and Le Chatelier's Principle
57
What is Le Chatelier's principle?
if stress is applied, the equilibrium will shift in a way that relieves stress
58
What is the Haber process?
creation of ammonia