Quiz 2 - Chapter 15 and 16 Flashcards

1
Q

Acid vs Base

A

Acid: proton donor (H+), pH 0-6, sour, can dissolve metals, turns blue litmus paper red, neutralizes bases, citrus, vinegar, stomach acid
Base: proton acceptor (H+), pH 8-14, slippery, bitter taste, turns red litmus paper blue, neutralizes acids

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2
Q

How to identify acids?

A
  • H in front

- carboxylic acid= ends in -COOH

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3
Q

How to identify bases?

A
  • ends in OH
  • also involves amines (N)
  • group 1 or 2 metal with hydroxide
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4
Q

Arrhenius definition of acids and bases

A

Acid: H+ donor
Base: OH- donor

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5
Q

Bronsted-Lowry definition of acids and bases

A

Acid: proton (H+) donor
Base: proton (H+) acceptor

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6
Q

Amphoteric

A
  • substance can act as an acid or a base

- water is the most common

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7
Q

Conjugate acid-base pairs

A

Two substances related to each other by transfer of a proton

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8
Q

Acid ionization constant equation

A

Ka = concentrations of products / concentrations of reactants

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9
Q

What happens to the reaction if:
A) Ka>1
B) Ka<1

A

A) when Ka>1, products are favoured, strong acid

B) when Ka<1, reactants are favoured, weak acid

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10
Q

Characteristics of strong acids?

A

They completely dissociate (complete ionization) and have very large Ka values, weak attraction, Products is H30+

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11
Q

What are some examples of strong acids?

A
HCl (hydrochloric acid)
HBr (hydrobromic acid)
HI (hydriodic acid)
HNO3 (nitric acid)
HClO4 (perchloric acid)
H2SO4 (sulfuric acid)
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12
Q

Characteristics of weak acids?

A

Have small Ka value, only partially dissociate (partial ionization), reaction always has reversible arrows, strong attraction

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13
Q

Characteristics of strong bases?

A

Completely dissociate (complete ionization), gives OH- as a product, have very large Kb values, weak attraction

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14
Q

What are some examples of strong bases?

A
LiOH (Lithium hydroxide)
NaOH (Sodium hydroxide)
KOH (Potassium hydroxide)
Sr(OH)2 (Strontium hydroxide) 
Ca(OH)2 (Calcium hydroxide)
Ba(OH)2 (Barium hydroxide)
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15
Q

Characteristics of weak bases?

A

Have small Kb value, only partially dissociate (partial ionization), reaction always has reversible arrows, strong attraction

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16
Q

What is the equation for the water ionization constant? How does it apply to Ka and KB?

A

Kw=[H3O+][OH-]
Kw= 1.010^-14 at 25 degrees Celsius
Kw=Ka
Kb (conjugate acid and conjugate base)

17
Q

What is the equation to calculate the pH using the concentration of H3O+? What about pOH?

A

pH=-log[H3O+]
pOH=-log[OH-]
14=pH+pOH

18
Q

How can you calculate the pH or pOH of a strong acid and a strong base? What about for a weak acid or base?

A

Concentration of strong acid=concentration of H3O+ then find pH
Concentration of strong base=concentration of OH- then find pOH
For weak acids or weak bases, you need to use ice tables to find concentrations of H3O+ or OH-

19
Q

What is the formula for calculating percent ionization? What is this formula also used to determine?

A

Percent ionization = [H3O+]eq / [HA]in *100
Used to see if we can make the x=0 assumption (must be below five percent to make this assumption!)
Percentage of the acid that ionizes (remember strong acids completely ionize, so this applies for weak acids!)

20
Q

Polyprotic acid

A

Have two or more protons that can dissociate. So must calculate in two steps! Usually are stronger acids (more H=more acidic)