Quiz 2 - Chapter 15 and 16 Flashcards
Acid vs Base
Acid: proton donor (H+), pH 0-6, sour, can dissolve metals, turns blue litmus paper red, neutralizes bases, citrus, vinegar, stomach acid
Base: proton acceptor (H+), pH 8-14, slippery, bitter taste, turns red litmus paper blue, neutralizes acids
How to identify acids?
- H in front
- carboxylic acid= ends in -COOH
How to identify bases?
- ends in OH
- also involves amines (N)
- group 1 or 2 metal with hydroxide
Arrhenius definition of acids and bases
Acid: H+ donor
Base: OH- donor
Bronsted-Lowry definition of acids and bases
Acid: proton (H+) donor
Base: proton (H+) acceptor
Amphoteric
- substance can act as an acid or a base
- water is the most common
Conjugate acid-base pairs
Two substances related to each other by transfer of a proton
Acid ionization constant equation
Ka = concentrations of products / concentrations of reactants
What happens to the reaction if:
A) Ka>1
B) Ka<1
A) when Ka>1, products are favoured, strong acid
B) when Ka<1, reactants are favoured, weak acid
Characteristics of strong acids?
They completely dissociate (complete ionization) and have very large Ka values, weak attraction, Products is H30+
What are some examples of strong acids?
HCl (hydrochloric acid) HBr (hydrobromic acid) HI (hydriodic acid) HNO3 (nitric acid) HClO4 (perchloric acid) H2SO4 (sulfuric acid)
Characteristics of weak acids?
Have small Ka value, only partially dissociate (partial ionization), reaction always has reversible arrows, strong attraction
Characteristics of strong bases?
Completely dissociate (complete ionization), gives OH- as a product, have very large Kb values, weak attraction
What are some examples of strong bases?
LiOH (Lithium hydroxide) NaOH (Sodium hydroxide) KOH (Potassium hydroxide) Sr(OH)2 (Strontium hydroxide) Ca(OH)2 (Calcium hydroxide) Ba(OH)2 (Barium hydroxide)
Characteristics of weak bases?
Have small Kb value, only partially dissociate (partial ionization), reaction always has reversible arrows, strong attraction
What is the equation for the water ionization constant? How does it apply to Ka and KB?
Kw=[H3O+][OH-]
Kw= 1.010^-14 at 25 degrees Celsius
Kw=KaKb (conjugate acid and conjugate base)
What is the equation to calculate the pH using the concentration of H3O+? What about pOH?
pH=-log[H3O+]
pOH=-log[OH-]
14=pH+pOH
How can you calculate the pH or pOH of a strong acid and a strong base? What about for a weak acid or base?
Concentration of strong acid=concentration of H3O+ then find pH
Concentration of strong base=concentration of OH- then find pOH
For weak acids or weak bases, you need to use ice tables to find concentrations of H3O+ or OH-
What is the formula for calculating percent ionization? What is this formula also used to determine?
Percent ionization = [H3O+]eq / [HA]in *100
Used to see if we can make the x=0 assumption (must be below five percent to make this assumption!)
Percentage of the acid that ionizes (remember strong acids completely ionize, so this applies for weak acids!)
Polyprotic acid
Have two or more protons that can dissociate. So must calculate in two steps! Usually are stronger acids (more H=more acidic)