Quiz 1: Part 2 Flashcards
Ionic Bonds
- occurs between metal and non-metal atoms
- large difference in electronegativity
Ionic Bonds: Electrostatic Attraction
metals losing one or more electron, leading to the positive charge and non-metal will gain the electron leading to negative charge
Covalent Bonds
- between atoms with similar electronegativities
- usually between non-metal atoms
- atoms share one pair of electrons to form a stable configuration
Metallic Bonds
- occurs between metal atoms
- sea of electrons or electron cloud
- attraction between metal and ions and electrons
Primary Bonds
atom to atom attraction force
Secondary Bonds
attraction force between molecules or intermolecular force, weak
Types of Secondary Bonds
- Van der waals
- a. Dipole
- b. london - Hydrogen
Van der Waals: Dipole
two atoms with equal and opposite electron charges
Van der Waals: London
- happens during the rapid motion of electron in orbit around the molecules
- temporary dipoles form when electrons are on one more side
Secondary: Hydrogen
- dipole-dipole interactions
- occurs when hydrogen is covalently bonded with highly electronegative atom; ex: nitrogen, oxygen, fluorine
- created by electron motion
- crucial in biological molecules
Crystalline Structures
- uniformed, reoccurring positions
- replication capabilities
- all metals, polymers, and ceramics have crystalline structures
Non-Crystalline Structures
amorphous
Types of Crystal Structures in Metal
- BCC: Body Center Cubic
- FCC: Face Center Cubic
- HCP: Hexagonal Close Cubic
Imperfections: Point Defects
- Vacancy
- Ion-Pair
- interstitialcy: distorted pattern
- Frenkel defect: displaced
Imperfections: Line Defects
- Edge dislocation
- Screw dislocation
Imperfections: Surface Defects
- Outside of Surface
- Inside (Grain Boundaries)
Reasons for Imperfections
- manufacturing process
- external stress & deformations
Slip
plastic deformation; crystals subjected to mechanical stress and slip across another
Slip Sequence
BCC > FCC > HCP : least amount of atoms / forces, most to slip >
Edge Dislocation
is subjected to shear stress, deforms easily
Plastic Deformation
atoms on one side of plane are shifted to form a mirror image on other side