Quiz 1 Flashcards

1
Q

List the principal quantum numbers

A

n, l, ml, ms

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2
Q

n

A
1, 2, 3, 4...
Energy level (the 2 in 2s)
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3
Q

l

A
determines the shape of the orbital
0 = s
1 = p
2 = d
3 = f
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4
Q

ml

A

the range of integers between positive and negative orbital shape.
+l … 0 … -l

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5
Q

ms

A

spin: either +.5 or -.5

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6
Q

Molecular Shapes

A
Linear
Trigonal Planar
Tetrahedral 
Trigonal Bi-pyramidal 
Octahedral
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7
Q

Atomic Radii trend

A

Bottom left is best

opposite of ionization energy

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8
Q

Ionization Energy

A

Top right is best, which means bottom left are more reactive elements.
IE is the amount of energy needed to pull off electrons. First group just gives em up.

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9
Q

Electron Affinity

A

Amount of energy released when an electron is added to a neutral atom. More negative (energy released) as you move right across table.

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10
Q

Electronegativity

A

Highest in top right corner of table (ignoring noble gasses)
Measure of the tendency of an atom or molecule to attract electrons.
If EN is similar, a bond is more likely

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11
Q

Gerade

A

Sigma bonding

Pi anti-bonding

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12
Q

Ungerade

A

Sigma anti-bonding

Pi bonding

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13
Q

Node types

A

Angular node:
S has none
P has 1
D has 2

Radial node:
4D has 1

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14
Q

Polarizeability

A

Large and charged are highly polarizeable

No noble gas configuration helps

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15
Q

Bonding MO vs Non-bonding MO

A

bonding is lower in energy

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16
Q

Bond Order

A

used to determine number of bonds in product
(Bonding - AB) / 2

A higher bond order means more bond energy and shorter bond length