quantum physics Flashcards

1
Q

what is the photoelectric effect?

A

process in which electrons are emitted from a metal surface when electromagnetic radiation of sufficiently high frequency is incident on the surface

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2
Q

what is a photoelectron?

A

electron emitted from the surface of a material due to the incident electromagnetic radiation

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3
Q

what happens when EM radiation is incident on emitter such that the collector is sufficiently positive?

A
  • every single photoelectron is attracted to C
  • rate of emission of photoelectrons = rate at which photoelectrons reach C
  • ammeter reads a constant saturated/max photocurrent
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4
Q

what happens when EM radiation is incident on emitter such that the collector is sufficiently negative?

A
  • most energetic photoelectrons do not have sufficient energy to reach C
  • photocurrent is zero
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5
Q

define stopping potential

A

magnitude of the negative potential of collector wrt emitter which prevents the most energetic photoelectrons from reaching the collector, results in zero photocurrent

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6
Q

what are the observations of photoelectric effect?

A
  1. saturated photocurrent is proportional to the intensity of the monochromatic EM radiation at a constant frequency
  2. existence of the threshold frequency (below which no emission of photoelectrons occurs irrespective of the intensity of the EM radiation
  3. max KE independent of intensity (energies emitted increases linearly with frequency)
  4. insignificant time lag (almost immediate emissions)
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7
Q

formula for the quantum theory of light

A

E = hf = hc/lumda

where
E = energy carried in EACH quantum emitted
h = 6.33 * 10^-34
f = frequency
c = 3.0*10^8

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8
Q

define a photon

A

quantum of electromagnetic energy

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9
Q

define the work function energy of a metal

A

the minimum amount of energy necessary for an electron to escape from the surface of a material

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10
Q

what is einstein’s photoelectric equation?

A

photon energy = work function energy + maximum KE of a photoelectron

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11
Q

relate max KE with stopping potential

A

EK max = eVs

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12
Q

what are the formulas for the particulate nature of light?

A

lumda = h/p
p = hf/c

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13
Q

how to prove light behaves as a wave?

A

interference / diffraction of light

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14
Q

how to prove light behaves as particles?

A

photoelectric effect

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15
Q

electrons behave as particles

A

electrons undergo collision, have mass and charge

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16
Q

electrons behave as a wave

A

electron diffraction

17
Q

key features of the energy level diagram

A
  • ground state = lowest energy level (n=1)
  • higher energy levels –> excited state
  • n = infinity (0 eV) –> electron escaped from atom
  • lower energy –> more negative energy value = more stable states
  • ionisation energy from n = 1 –> n = infinity
18
Q

what is ionisation

A

process of creating charged particles

19
Q

what is excitation

A

process whereby atoms absorb energy without ionisation

20
Q

what are the two main sources of energy that can cause the electron to be ionised or excited to a higher energy state

A
  1. particle collision (high speed particle collides and imparts energy to an atom –> excited electron at a higher energy level **energy of electrons need not match)
  2. photons (for an orbital electron to gain energy, photon energy must be exactyl equal to energy difference btwn 2 levels in the atom)
21
Q

explain emission line spectrum

A

gases (H,Ne) in a discharge tube at low pressure with high voltage applied btwn ends of a tube, gas glows, light emitted from tube.
light examined through a diffraction grating with a spectrometer –> distinct lines observed –> emission line spectrum

gas heated/bombarded by electrons –> electrons in gas excited to higher energy levels
de-excitation –> photons emitted with energy corresponding to energy difference btwn 2 energy levels

energy levels & differences are discrete –> corresponds to series of lines on spectrum

discrete bright lines of definite wavelength on a dark backrground