Quantum and nuclear physics Flashcards
Observations of the photoelectric effect showed that:
- below a certain threshold frequency (fo) of incident light no electrons were emitted, no matter how bright the light is (each metal has own fo)
- above fo the maximum Ek of the e is dependent on the frequency of the incident light
- if the intensity of the incident light is increased the freq. = same, more e were emitted but the energy of the e did not change
- there was no delay between the incident light arriving ad the e being emitted
Why could these observations of photoelectric effect not be explained by light being a wave
- the energy of a wave is prop. to square of amplitude so a brighter more intense light should emit e with more energy
- the fo cannot be explained as by increasing intensity eventually enough energy should arrive so that e could be emitted no matter the freq.
- there should be a time delay between light arriving and e being emitted
How were the observations from the photoelectric effect explained by Einstein
- e at the surface of the metal need a min amount of energy to escape (work function ø)
- incident light arrives in photons
- the energy of the photon depends on the frequency of the light
- the higher the intensity the more photons arrive per second but the energy level does NOT change
- e in the metal will absorb the photons but only ONE photon can be absorbed per e
Stopping voltage
the value of voltage where the current is just zero as the electrical energy matches the Ek of the e
used to calc. Ek of e
De Broglie Wavelength
proposed that particles should also have a wave nature as light could behave as a particle
it is dependent upon momentum
p = h/wavelength
How did Davisson and Germer show that e could act as waves
they accelerated e at Ni and observed
expected:
- the Ni is rough on the microscopic level
- therefore the e were expected to be reflected diffusely (across a range of angles)
actual:
- the reflected e produced intensity peaks at specific angles depending on the potential difference used to accelerate the electrons
explained:
- the crystal surface acted as a diffraction grating causing the e to diffract and produce an interference pattern
- the angle of maximum e intensity was found to match that of the e’s calculated wavelength
wavelength = h/√(2meV)
Bohr model of the atom
- e can exist in stationary states (i.e. remain in an orbit without emitting EM rad.)
- e can move between these states by absorbing or emitting a photon
dif. in energy state is given by E = hf - the angular momentum of an e in a stationary state is quantised in integral values of h/2pi
Angular momentum
is the product of linear momentum and the radius of an orbit (mvr)
Wavefunction
is the amplitude of the de Broglie wavelength
the wavefunction squared gives the probability per unit volume of finding the electron at that position (also called probability density)
Similarities and differences in Bohr and Schrodinger’s models
similarity:
both have the same energy levels for e
differences:
- e location: Bohr has e in orbits of specific radii and Schrodinger has the wavefunction of the e determining the probability of finding it at any position
- nature of the e: Bohr has it as a particle and Schrodinger has it as a wave
Heisenberg’s Uncertainty Principle
the simultaneous measurements of the position and momentum of a particle will always have some uncertainty
What is quantum tunneling?
a process whereby quantum particles can overcome potential barriers deemed impossible according to classical physics
possible due to the wavefunction
Factors that affect quantum tunneling
- the greater the mass of the particle the lower the prob.
- the greater the width of the barrier the lower the prob.
- the greater the energy dif. between the energy of the particle and the energy required to climb the barrier the lower the prob.
Examples of quantum tunneling
Relatively low fusion that occurs in main sequence stars like the sun
alpha particle decay:
the strong nuclear force provides a potential barrier, the wavefunction of the alpha particle extends beyond the potential barrier allowing it to happen
radioactive substances with a long half-life have a higher and wider potential barrier than those with a short half-life
Nuclear density
- assume nucleus is spherical,
V = 4/3 pi R^3 = 4/3 pi Ro^3 A - density = mass/volume = (A u)/(4/3 pi Ro^3 A)
= (3 u)/(4 pi Ro^3)
therefore as all values in this formula are constant all nuclei have the same density