Quantum Flashcards

0
Q

Wavelength and frequency are _______ related.

A

inversely

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1
Q

All __________ waves, including visible light, travel at the speed of light, or ____________ m/s.

A

electromagnetic, 3.00 * 10^8 m/s

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2
Q

Atomic emission spectrum of an element

A

The set of frequencies of the electromagnetic waves emitted by atoms of the element

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3
Q

The distinct wavelengths that appear on hydrogen’s emission spectra are explained by ________

A

the different energy levels of hydrogen’s electrons

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4
Q

Describe the 4 quantum numbers.

A

PQN, SQN, m(sub)l, m(sub)s

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5
Q

Aufbau principle

A

Electrons are added to the orbitals of lowest energy first

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6
Q

Puali’s exclusion principle

A

Each orbital within a subshell can accommodate no more than two electrons and these electrons must have opposite spins

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7
Q

Hund’s principle

A

When electrons occupy orbitals of equal energy, one electron enters each orbital until all the orbitals contain one electron with parallel spins

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8
Q

Heisenberg’s uncertainty principle

A

You can never know the position and momentum of a particle at a given time

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9
Q

Total number of electrons within a given energy level is ____

A

2n^2

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10
Q

_____ notation and _____ notation follow the aufbau sequence, while ____ notation does not

A

Box, noble gas, spectroscopic

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11
Q

In 1900, Planck stated that there is a concept called a quantum, which is _______

A

a minimum quantity of energy that can be emitted at any time and it exists in small, measurable packets

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12
Q

After hearing Planck’s Quantum Theory, Bohr proposed that electrons maintain a __________ when they move around the nucleus.

A

energy level

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13
Q

de Broglie suggested that ________

A

If electromagnetic waves can behave as particles, then moving particles can have wave properties

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14
Q

Shape of s orbital

A

spherical

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15
Q

Shape of p orbital

A

dumbbell shape

16
Q

Shape of d orbital

A

cloverleaf

17
Q

Shape of f orbital

A

doughnut shape

18
Q

The photoelectric effect was coined by ____

A

Einstein

19
Q

Photoelectric effect

A

When light shines on a metal, the photons collide with the electrons from the metal, ejecting these electrons

20
Q

Lyman series

A

Anything to 1 (ultraviolet)

21
Q

Balmer series

A

Anything to 2 (visible light)

22
Q

Paschen series

A

(anything to 3) high IR

23
Q

Brackett series

A

anything to 4 (mid-IR region)

24
Q

Pfund series

A

Anything to 5 (low IR region)

25
Q

Weakness of the Rydberg equation?

A

It only works for hydrogen

26
Q

List the series of spectral lines in order.

A

Balmer, Lyman, Paschen, Brackett, Pfund

27
Q

Planck’s constant

A

6.63 * 10^-34

28
Q

Avogadro’s number

A

6.022 * 10^23

29
Q

JW Dobereiner

A

Observed the existence of triads of similarly behaving elements

30
Q

Newlands

A

Observed that when elements were arranged according to increasing atomic mass, every eighth element had similar properties (law of octaves)

31
Q

Henry Moseley

A

Proposed Periodic Law, that properties of elements are based on atomic numbers, not atomic mass

32
Q

Azimuthal Arrangement

A

s & p blocks are group A (representative elements), d block group B (transition elements), f block (inner transition elements)

35
Q

as you move from left to right, what decreases?

A

ionic size of cations and ionic size of anions, atomic radii,

36
Q

As you move from left to right, what increases?

A

electronegativity, electron affinity, ionization energy

37
Q

What is constant as you move left and right?

A

shielding effect

69
Q

As you move down the columns of the periodic table, what decreases?

A

ionization energy, electron affinity, electronegativity

70
Q

As you move down the columns, what increases?

A

shielding effect, atomic radii, nuclear charge, ionic size