Quanta to Quarks Flashcards
what experiment helped to provide evidence for rutherfords model of the atom?
the gold foil experiment( or rutherfords scattering experiment)
who performed the gold foil experiment?
hans ginger ands Ernest Marsden under the direction of Rutherford
what did the gold foil experiment involve and what were the results?
-alpha particles were emitted from a source, through a collimator at a piece of thin gold foil, with a detector situated on the other side of the foil
most of the particles passed through the foil with little to no deflection, but 1 in 8000 alpha particles were deflected back at an angle greater than 90 degrees, which had been identified via the detector
what did Rutherford propose as a result of the gold foil experiment?
he proposed that the only way that the alpha particles could be deflected through large angles was if all the atoms positive charge and nearly all of its mass was concentrated in a small dense nuclear with the electrons a very large distance away.
the fact that most of the alpha particles went through the foil led Rutherford to believe that the atom was mostly to a high degree empty space
by using the results of the gold foil experiment, Rutherford found that the size of the atom was…
10^-10m in diameter
Rutherford found that the size of the nucleus was…
10^-14m in diameter
compared with the size of the atom, the nucleus is…
10000x smaller
like a grain of sand in my bedroom
what were the problems with rutherfords model of the atom?
- if the electrons circled the nucleus of the atom like planets orbiting the sun, they would be accelerating. but accelerating charges are known to hit electromagnetic radiation, and so the electrons would be constantly losing energy and spiral into the nuclear and the atom should collapse upon itself. but this isnt the case obviously
- rutherfords model could not exactly describe what the nucleus was made of, how the electrons were arranged and could not explain why the electrons were not attracted to the positive nucleus
what was the good thing about rutherfords model of the atom?
the model was essentially a simplified version of the model that is used today.
it was ground breaking at the time as it was a step in the right direction for other scientists to build upon
what was bohrs first postulate and what did it account for?
1) electrons can revolve/exist in stationary states of stability and emit no energy when in these states. they can revolve in certain allowed orbits
this idea accounted for the observed stability of atoms. why these stationery states existed was unknown, but it was a fact that they did exist
what was bohrs second postulate and what did it account for?
2) energy is lost or gained by an electron as it moves from state to state, and when it moves from a higher energy state to a lower energy state, it releases a photon with energy equal to a difference between the states( and therefore a characteristic frequency)
this photon energy is quantised by the Planck relationship/equation
this postulate accounted for the line emission spectra of atoms
- emission(or absorption) of energy is discontinuous and corresponds to a transition between two stationary states
- a transition between different states will lead to different frequencies or colours
what was bohrs third and final postulate and what did it mean?
3) electron angular momentum in a stationery state is equal to an integer value of h/2(pie)
this postulate sets limits on the radius of the allowed orbits
what were the two general limitations of the Bohr model of the atom?
- still did not explain why there is no energy emission by the accelerating electrons as predicted by Maxwell, instead it was simply assumed that this didn’t happen
- there was no evidence for the existence of the Bohr model to grant it scientific credibility
what were the four areas of the emission of spectra that the Bohr model couldn’t explain and describe them
-the spectra of large atoms with more than one electron
only one electron ions or atoms applied to bohrs model. this is because for larger atoms outer electrons are shielded from the nucleus by the inner electrons. interactions between electrons also result in different energy levels
-the relative intensity of spectral lines
when the spectrum for hydrogen was closely examined it was noted the emission lines varied in intensity , some were quite intense and others were less intense, some were sharp, others were diffuse
-the existence of hyperfine lines
as spectroscopes got better, spectra could be more closely examined, and it was found that each line actually consisted of many other small lines
-the Zeeman effect
in 1896 a dutch physicist Pieter Zeeman found that when he placed a source of sodium emission light between the poles of a strong magnet the lines split into three
some even split into 15 in other atoms
what was de broglies big idea?
suggested that any fundamental particle had wave-particle duality
via de broglies idea of wave-particle duality, what can exist?
matter waves and things like tennis balls or elephants can have whats called a de Broglie wavelength
what were the impacts of de-broglies ideas?
-provided a model to accompany bohrs first postulate that there were stable orbits where electrons did not emit any energy
this gave the Bohr model the credibility it required to be accepted and developed upon by the scientific community, which provided vital in understanding the structure of the atom
-de broglies principles has also been used to make electron microscopes, exploiting the wave particle duality of them.
these are used to image objects at far greater resolution than was possible with light due to the smaller wavelength of electrons
-de broglies proposal also reconciled Einsteins theory of light with classical physics by showing that light could have both wave and particle nature
define diffraction
the bending of light around obstructions. purely a wave property
what does the amount of diffraction depend upon?
it depends on the size of the obstruction, and is greatest when the obstruction is of the same order as the size of the diffracting waves wavelength
why does interference occur when a wave is diffracted?
when a wave diffracts around an obstruction,
the corners of that object act as point sources for the wave, resulting in a curved wave that radiates outward
there now exist two waves, the point source waves and the original that can super impose one another
if the two waves during diffraction arrive at a particular point in phase, such that a crest meets a crest and a trough meets a trough,….
they reinforce each other and constructively interfere
if the two waves during diffraction arrive at a particular point where a crest meets a trough,…..
they effectively cancel each other out and therefore destructively interfere
via diffraction, interference creates…
a combination of bright(constructive) and dark (destructive) fringes. if the obstruction is circular, light and dark rings form
from de broglies hypothesis, what it possible to be derived?
bohrs third postulate