Quanta to Quarks Flashcards
what experiment helped to provide evidence for rutherfords model of the atom?
the gold foil experiment( or rutherfords scattering experiment)
who performed the gold foil experiment?
hans ginger ands Ernest Marsden under the direction of Rutherford
what did the gold foil experiment involve and what were the results?
-alpha particles were emitted from a source, through a collimator at a piece of thin gold foil, with a detector situated on the other side of the foil
most of the particles passed through the foil with little to no deflection, but 1 in 8000 alpha particles were deflected back at an angle greater than 90 degrees, which had been identified via the detector
what did Rutherford propose as a result of the gold foil experiment?
he proposed that the only way that the alpha particles could be deflected through large angles was if all the atoms positive charge and nearly all of its mass was concentrated in a small dense nuclear with the electrons a very large distance away.
the fact that most of the alpha particles went through the foil led Rutherford to believe that the atom was mostly to a high degree empty space
by using the results of the gold foil experiment, Rutherford found that the size of the atom was…
10^-10m in diameter
Rutherford found that the size of the nucleus was…
10^-14m in diameter
compared with the size of the atom, the nucleus is…
10000x smaller
like a grain of sand in my bedroom
what were the problems with rutherfords model of the atom?
- if the electrons circled the nucleus of the atom like planets orbiting the sun, they would be accelerating. but accelerating charges are known to hit electromagnetic radiation, and so the electrons would be constantly losing energy and spiral into the nuclear and the atom should collapse upon itself. but this isnt the case obviously
- rutherfords model could not exactly describe what the nucleus was made of, how the electrons were arranged and could not explain why the electrons were not attracted to the positive nucleus
what was the good thing about rutherfords model of the atom?
the model was essentially a simplified version of the model that is used today.
it was ground breaking at the time as it was a step in the right direction for other scientists to build upon
what was bohrs first postulate and what did it account for?
1) electrons can revolve/exist in stationary states of stability and emit no energy when in these states. they can revolve in certain allowed orbits
this idea accounted for the observed stability of atoms. why these stationery states existed was unknown, but it was a fact that they did exist
what was bohrs second postulate and what did it account for?
2) energy is lost or gained by an electron as it moves from state to state, and when it moves from a higher energy state to a lower energy state, it releases a photon with energy equal to a difference between the states( and therefore a characteristic frequency)
this photon energy is quantised by the Planck relationship/equation
this postulate accounted for the line emission spectra of atoms
- emission(or absorption) of energy is discontinuous and corresponds to a transition between two stationary states
- a transition between different states will lead to different frequencies or colours
what was bohrs third and final postulate and what did it mean?
3) electron angular momentum in a stationery state is equal to an integer value of h/2(pie)
this postulate sets limits on the radius of the allowed orbits
what were the two general limitations of the Bohr model of the atom?
- still did not explain why there is no energy emission by the accelerating electrons as predicted by Maxwell, instead it was simply assumed that this didn’t happen
- there was no evidence for the existence of the Bohr model to grant it scientific credibility
what were the four areas of the emission of spectra that the Bohr model couldn’t explain and describe them
-the spectra of large atoms with more than one electron
only one electron ions or atoms applied to bohrs model. this is because for larger atoms outer electrons are shielded from the nucleus by the inner electrons. interactions between electrons also result in different energy levels
-the relative intensity of spectral lines
when the spectrum for hydrogen was closely examined it was noted the emission lines varied in intensity , some were quite intense and others were less intense, some were sharp, others were diffuse
-the existence of hyperfine lines
as spectroscopes got better, spectra could be more closely examined, and it was found that each line actually consisted of many other small lines
-the Zeeman effect
in 1896 a dutch physicist Pieter Zeeman found that when he placed a source of sodium emission light between the poles of a strong magnet the lines split into three
some even split into 15 in other atoms
what was de broglies big idea?
suggested that any fundamental particle had wave-particle duality
via de broglies idea of wave-particle duality, what can exist?
matter waves and things like tennis balls or elephants can have whats called a de Broglie wavelength
what were the impacts of de-broglies ideas?
-provided a model to accompany bohrs first postulate that there were stable orbits where electrons did not emit any energy
this gave the Bohr model the credibility it required to be accepted and developed upon by the scientific community, which provided vital in understanding the structure of the atom
-de broglies principles has also been used to make electron microscopes, exploiting the wave particle duality of them.
these are used to image objects at far greater resolution than was possible with light due to the smaller wavelength of electrons
-de broglies proposal also reconciled Einsteins theory of light with classical physics by showing that light could have both wave and particle nature
define diffraction
the bending of light around obstructions. purely a wave property
what does the amount of diffraction depend upon?
it depends on the size of the obstruction, and is greatest when the obstruction is of the same order as the size of the diffracting waves wavelength
why does interference occur when a wave is diffracted?
when a wave diffracts around an obstruction,
the corners of that object act as point sources for the wave, resulting in a curved wave that radiates outward
there now exist two waves, the point source waves and the original that can super impose one another
if the two waves during diffraction arrive at a particular point in phase, such that a crest meets a crest and a trough meets a trough,….
they reinforce each other and constructively interfere
if the two waves during diffraction arrive at a particular point where a crest meets a trough,…..
they effectively cancel each other out and therefore destructively interfere
via diffraction, interference creates…
a combination of bright(constructive) and dark (destructive) fringes. if the obstruction is circular, light and dark rings form
from de broglies hypothesis, what it possible to be derived?
bohrs third postulate
how did heisenberg contribute to the development of atomic theory?
-devised matrix mechanics to explain the atom in terms of quantum probabilities, rather than mixing classical quantum theory which bohr had down
this lead to an entirely quantum theory of the atom, helping to mathematically understand its nature
-he devised the heisenberg uncertainty principle, effectively says that for every elementary particle, the more pricely the position is dtermined, the less precisely the momentum is known in the instant and vice versa
this changed the way science viewd atomic structure, by this theory electron orbits postulated by bohr could not exist, it led to the idea of electron clouds rather than orbits where an electrons position could not be determined due to a statistic probability
this uncertainty principle is the most central principles of quantum mechanics, tha knowledge of one thing can be mutaully exclusive to knowledge of another
made physicists rethink the way they designed their experiments and caused them to have more realistice expectations regarding the precision they could hope to achieve with their measurement
what ideas did pauli propose which contributed to the worlds understanding og atomic theory?
- took the quantum mechanical medoel which was entirely theoretical and applied it to the hydrogen atom to derive rydberg constant and to devleop Balmers equation
- pauli used bohrs idea of electron shells and developed the exlusion principle in which he introduced a new quantum number known as spin to explain the max no. of electrons in energy levels. no two electrons can have the same set of 4 quantum numbers
- pauli proposed the existence of the neutrino, another significant subatomic particle
how did paulis idea of the exclusion principle impact on quantum theory?
- paulis exclusion principle accounted for the max no. of electrons in each shel around a nucleus, and derived it to be 2n^2 where n is the shell number
- his principle was later discovered to aply to all fermions(a class of sub particles in which the electron is one)
- provided a quantum explanation for the position of the first 20 elements in the periodic table
- explained why the heavier atoms are so much larger than the lighter ones—> the extra electrons have to find space in new orbitals further and further out. also explains why even at low temp, most conduction electrons in a matallic crystal are still in high energy states, and very mobile
- able to exaplin the zeeman effect
what do you classify protons and neutrons as?
nucleons
constrast the proton and the neutron
- both have a mass of the same order, but the neutron is slightly heavier
- the proton has the same magnitude of charge as an electron, but opposite in sign
- the neutron has no charge. this means protons are affected by magnetic fields and electric fields while neutrons arent
whats the mass of a proton and a neutron?
1.673 and 1.675 respectively to the order 10^-27Kg
in 1930, what did german physicist and mathematician walther bothe and his student herbet becker discover?
discovered that bombarding berylium with alpha particles resulted in the emission of a penetrating type of radiation. this radiation proved not to be gamma rays even though these were expected penetrating radiation as they could not be detected using a cloud chamber and didnt appear to be a particle
what did english physist james chadwick suggest was the nature of this penetrating radiation?
he suggested that this radiation was rutherfords neutron
how did chadwick detect the neutrons?
he placed a parrafin wax, rich with hydrogen, in front of the berylium. because uncharged neutrons were hard to detect, as they caused little to no ionisation, the addiation of this wax would be used to ehance the detection through a detector
-the neutrons ejected from the berylium would eject protons from the wax as a result of elastic collisions, and as the collisions cause ionisation they’re readily detected
what laws did chadwick use to prove the existence of the neutron?
law of conservation of energy and law of conservation of mass and number
how did chadwick use the law of conservation of energy to prove the existence of the neutron?
well, the energy of the released protons had been measured to be 5 milli electron vol, implying that if the unknown radiation was gamma radiation, it would have had an energy of 50 milli electron volts
this was problematic because the original alpha particles had only energy of 5 milli electron volts
this implied that there was a tenfold increase from the alphar particles in creating the unkown radiation, and hence this violated the law of conservation of energy
but, chadwick realised that a neutral particle such as a proton would be capable of colliding with a proton and imparting the observed momentum without violating conservation laws.
thus the law of conservation of momentum was vitally important for chadwic and his discovery of the neutron
how did chadwick use the law of conservation of mass and number to prove the existence of the neutron?
by adding the mass numbers, according to conservation of atomic mass laws, there would have been present an unkown particle with the same mass as a neutron to explain the result of the investigation
thus through conservation of mass chadwick was able to prove the existence of the neutron (and show that initially observed radiation was infact a particle)
why do we need a strong nuclear force to exist?
because, in an atom, the electrostatic repulsion between protons is far to high compared to the gravitational attraction that pulls them close together. if the force didnt exist, all atoms would explode
infact, the gravitational force is so small that it is diregarded during calculations
what are the features of the strong nuclear force?
- the force neglects charge and is equal and similar between proton-proton, proton-neutron and neutron-neutron
- only acts between neighbouring nucleons, not the entire nucleus
- the strong nuclear force is known as the strongest known force in the universe
- the strong nuclear force is only
experienced over a very small range
at extremely short distances it is
repulsive, then it becomes attractive as distance increases, then increasingly weaker at larger distances
at distances over 2x10^15m, the force is effectively zero. if the distance between nucleons becomes less than 0.5 x 10^15m, the force is repulsive
there exists a balance of seperation where at a particular point, the two forces are balanced and the nucleus is stable
describe the trail of alpha particles in a cloud chamber and relate them to their properties
- forms strong trails because they are more highly charged, and therefore ionise mroe air as they travel( resulting in more condensation).
- their trails are also shorter than beta particles, becuase their strong charge causes them to attract electrons rapidly, so before they travel a long distance they get converted to neutral helium, and therefore can no longer ionise the air–> same reason that alphar radiation is both not very penetrative, yet highly dangerous inside the body
alpha trails are relatively straight, because the large mass of the alpha particle means that it will be deflected less by other particles as it travels
describe the trail of beta particles in a cloud chamber and relate them to their properties
- form less intense trails because their ionisation strength is not great
- react less with their surroundings, and hence travel a longer distance
-beta particles have a very low mass, and so are very susceptible to having their path changed through interactions/collisions with other particles.
however, their path is still quiete straight because of their heigh velocity and low charge which means that they are less liekly to have their path changed
what are the parts to a wilson cloud chamber?
-radiation source
-glass container filled with a supersaturated water or alcohol vapour.
the vapour can be made DIY by placing filter paper sealed in methylated spirits inside the container