Qualitative Tests Flashcards

0
Q

Alkenes

A

Addition of bromine water

Orange bromine solution decolourises

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1
Q

Alcohol (hydroxyl group)

A

PCl5
Steamy white fumes of HCl
Nucleophilic sub of -OH group with Cl

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2
Q

Halogenoalkanes

A
Make solution alkaline
Add HNO3 until just acidic
Add AgNO3 drop wise
Chloro = white ppt
Bromo = cream ppt
Iodo = yellow ppt
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3
Q

Carbonyl group

A

2,4 - DNP

Orange ppt

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4
Q

Aldehyde or Ketone

A

Fehlings
Aldehyde turns from blue to red
No change for ketones

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5
Q

Carboxylic Acid

A

Add sodium hydrogen carbonate solution

CO2 is produced which turns like water cloudy

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6
Q

Secondary alcohol

A

Iodoform test
Warm compound with a solution of iodine and NaOH
Yellow ppt with an antiseptic smell

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