Qualitative analysis: tests for ions Flashcards

1
Q

Why must the test for any ion be unique?

A

Wouldn’t be able to know what ion it was if more than one gave the same result innit

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2
Q

how to do a flame test?

A
  • Light bunsen burner to non-safety flame
  • Take a wire loop, dip it into hydrochloric acid, rinse in distilled water and hold it over a flame. It should produce no colour if it is clean.
  • Dip the wire loop into the metal
  • Hold it above the fire and use the colour to determine the ion
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3
Q

How to do a precipitation test?

A
  • Add sodium hydroxide solution to the compound
  • If a hydroxide precipitate forms, you can use the colour to tell which metal ion was there
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4
Q

How to do halide test?

A
  • add dilute nitric acid
  • add silver nitrate solution
  • nitric acid gets rid of carbonate ions because they confuse results
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5
Q

how to test for carbonate ions

A
  • Add dilute acids, mixture will fizz
  • carbonate reacts with acid to form carbon dioxide and water
  • Check gas produced is carbon dioxide by bubbling through limewater
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6
Q

How to test for sulfate ions

A
  • add hydrochloric acid, stops any other precipitation reactions
  • Add barium chloride
  • If there are sulphate ions, white precipitate of barium sulphate forms
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7
Q

lithium result

A

red flame

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8
Q

sodium result

A

yellow flame

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9
Q

potassium result

A

lilac flame

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10
Q

calcium test results

A
  • orange-red flame
  • White precipitate
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11
Q

copper test results

A
  • blue-green flame
  • blue precipitate
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12
Q

aluminium test results

A

precipitate: white at first. However, will dissolve and turn colourless when you add excess sodium hydroxide

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13
Q

Iron II results

A

Precipitate: Green

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14
Q

Iron III results

A

Precipitate: Brown

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15
Q

test for ammonium ions/ammonia

A
  • Add sodium hydroxide
  • Heat gently
  • Place damp red litmus paper over it
  • if it is ammonia, will turn blue
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16
Q

chloride test results

A
  • white precipitate silver chloride
17
Q

bromide test results

A
  • cream precipitate silver bromide
18
Q

iodide test results

A
  • yellow precipitate silver iodide
19
Q

How can you use instrumental methods of analysis?

A
  • Flame photometry uses photometer
  • Analyses spectra produced by ions
  • Sensitive, fast and accurate