qualitative analysis Flashcards

1
Q

describe the test for ammonium compounds

A
  • add NaOH
  • gently heat
  • place damp red litmus at top of tube (NH3 turns litmus blue)
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2
Q

describe the test for hydroxides

A

turns red litmus blue

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3
Q

describe the test for carbonates

A

turns limewater cloudy when bubbled through HCl

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4
Q

describe the test for sulfates

A
  • add HCl to remove carbonates
  • add BaCl2
  • white ppt forms
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5
Q

what is the order for qual analysis?

A

carbonate
sulfate
halide

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6
Q

why is there a specific order for qual analysis?

A

prevents false positives

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7
Q

iodine in water

A

brown

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8
Q

iodine in cyclohexane

A

purple

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9
Q

iodine vapour

A

colour

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10
Q

bromine in water

A

orange

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11
Q

bromine vapour

A

orange/brown

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12
Q

chlorine gas

A

pale green

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13
Q

silver iodide

A

yellow

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14
Q

silver chloride

A

white

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15
Q

silver bromide

A

cream

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16
Q

phenolphthalein in acid

A

colourless

17
Q

phenolphthalein in alkali

A

pink

18
Q

methyl orange in acid

A

red

19
Q

methyl orange in alkali

A

yellow

20
Q

potassium dichromate

A

orange

21
Q

Cr3+ in sulphuric acid

A

green

22
Q

Fe2+ (aq)

A

pale green

23
Q

Fe3+ (aq)

A

pale yellow

24
Q

Cu2+ (aq)

A

blue

25
Q

Mn2+ (aq)

A

pale pink

26
Q

Mn(OH)2

A

beige

27
Q

Cu(OH)2

A

light blue

28
Q

Cr(OH)3

A

grey green

29
Q

Fe(OH)2

A

green

30
Q

Fe(OH)3

A

brown

31
Q

[Cr(OH6]3-

A

dark green

32
Q

[Cr(NH3)6]3+

A

purple

33
Q

[Cu(NH3)4(H2O)2]2+

A

dark blue

34
Q

end point potassium manganate

A

permanent pink

35
Q

end point thiosulfate titration

A

colourless from blue/black