QA Flashcards
Test for gases (3 steps)
- Colour, odour
- Litmus test
- Confirmatory test
Test for H2
- Colourless, odourless
- No effect on moist litmus paper
- Place a lighted splint at the mouth of the test tube, lighted splint extinguishes with a ‘pop’ sound if Hydrogen is present
Test for O2
- Colourless, odourless
- No effect on moist litmus paper
- Place a glowing splint at the mouth of the test tube, glowing splint rekindles if Oxygen is present
Test for CO2
- Colourless, odourless
- Turns moist blue litmus paper red
- Bubble the gas through a test tube containing limewater. If a white ppt forms, gas present is CO2
Test for NH3
- Colourless, pungent smelling
- Turns moist red litmus paper blue
- Nil
Test for SO2
- Colourless, choking smell
- Turns moist blue litmus paper red
- Filter paper soaked in KMnO4 changes from purple to colourless
Test for Cl2
- Greenish-yellow, irritating smell
- Turns moist blue litmus paper red, then bleaches
- Nil
Test for H20
- Colourless, odourless
- No effect on moist litmus paper
- Anhydrous cobalt (II) chloride from blue to pink
Why must litmus paper be moist before testing
To allow for the dissociation of ions
Test for carbonate ions
Add dilute HCl, effervescence is observed (CO2)
Test for nitrate ions
Add aqueous NaOH, then warm gently with a piece of aluminium foil. Effervescence is observed (NH3)
Test for sulfate ions
Add dilute HNO3, then aqueous BaNO3. White ppt of BaSO4 forms
Test for chloride ions
Add dilute HNO3, then aqueous AgNO3. White ppt of AgCl forms
Test for iodide ions
Add dilute HNO3, then aqueous AgNO3. Yellow ppt of AgI forms
Test for cations: Al3+
White ppt in NaOH, soluble in excess to form colourless solution
White ppt in NH4OH, white ppt insoluble in excess
Test for cations: Pb2+
White ppt in NaOH, soluble in excess to form colourless solution
White ppt in NH4OH, white ppt insoluble in excess
Test for cations: Zn2+
White ppt in NaOH, soluble in excess to form colourless solution
White ppt in NH4OH, soluble in excess to form colourless solution
Test for cations: Cu2+
Light blue ppt in NaOH, blue ppt insoluble in excess
Light blue ppt in NH4OH, soluble in excess to form deep-blue solution
Test for cations: Fe2+
Green ppt in NaOH, green ppt insoluble in excess
Green ppt in NH4OH, green ppt insoluble in excess
Test for cations: Fe3+
Reddish-brown ppt in NaOH, reddish-brown ppt insoluble in excess
Reddish-brown ppt in NH4OH, reddish-brown ppt insoluble in excess
Test for cations: Ca2+
White ppt in NaOH, white ppt insoluble in excess
No visible change
Test for cations: NH4+
Ammonia produced on warming
No visible change
Test for cations: NH4+
Ammonia produced on warming
No visible change
Thermal decomposition: carbonate
CaCO3 -> CaO + CO2
Thermal decomposition: hydroxides
Ca(OH)2 -> CaO + H2O