properties of period 3 elements and their oxides Flashcards
what is more reactive, Na or Mg?
Sodium is more reactive than magnesium as it only has to lose one electron to form an ion, whereas magnesium has to lose two electrons. Therefore less energy is required to ionise sodium making it more reactive.
Na reaction with water.
Equation and observations
2Na(s)+ 2H2O(l) → 2NaOH(aq) + H2(g)
Reacts vigorously
forms a ball
fizzing
Mg reaction with water and steam
Equation and observations
Mg(s) + 2H2O(l) → Mg(OH)2(aq) + H2(g)
Bright white light
White solid
reacts faster with steam: Mg(s) + H2O(l) → MgO(s) + H2(g)
Na reaction with oxygen
Equations and observations
4Na (s) + O2 (g) → 2Na2O (s)
vigorous reaction
bright yellow flame
white solid
Mg reaction with oxygen
Equations and observations
2Mg (s) + O2 (g) → 2MgO (s)
vigorous reaction
bright white flame
white solid
more intense if lowered into jar of oxygen
Al reaction with oxygen
Equations and observations
Why does it seem to be unreactive?
4Al (s) + 3O2 (g) → 2Al2O3 (s)
fast reaction
powdered Al
bright white flame
white powder
always coated in a strongly bonded layer of oxide to prevent further reaction so seems unreactive
Si reaction with oxygen
Equations and observations
Si (s) + O2 (g)→ SiO2 (s)
slow reaction
powdered Si burns if strongly heated in oxygen
bright white sparkles
white powder
P reaction with oxygen
Equations and observations
4P (s) + 5O2 (g) → P4O10 (s)
White P is spontaneous combustion
white flame
white smoke
white solid
Red P must be heated before reaction
S reaction with oxygen
Equations and observations
S (s) + O2 (g) → SO2 (g)
gentle reaction
blue flame
For SO3 to form, a catalyst must be used and the reaction must take place at a very high temperature
The equation for this reaction is:
2S (s) + 3O2 (g) → 2SO3 (g)
Oxides of Na, Mg, Al
structure and bonding
giant ionic lattice
strong electrostatic forces of attraction between oppositely charged ions
spreads throughout compound
gives it a high melting point
lots of energy required to overcome
Bonding in Al2O3
ionic/covalent
metal + non-metal
due to it being a small ion with a large positive charge
the Al+3 ion can polarize electron charge from O-2 ion. That can give the bond some covalent character.
SiO2
structure and bonding
macromolecular
many strong covalent bonds spread throughout structure
a lot of energy required to break covalent bonds
oxides of P,S
structure and bonding
simple molecular
weak wan der waals
trends in melting points for oxides
Na2O < MgO > Al2O3 >
SiO2 > P4O10 > SO3 > SO2
Na2O reaction with water
equations, ionic , PH
Na2O + H2O → 2NaOH
Na2O + H2O → 2Na+ + 2OH-
PH 13-14
strongly alkaline