properties of period 3 elements and their oxides Flashcards

1
Q

what is more reactive, Na or Mg?

A

Sodium is ​more reactive​ than magnesium as it only has to lose one electron to form an ion, whereas magnesium has to lose two electrons. Therefore​ less energy is required ​to ionise sodium making it more reactive.

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2
Q

Na reaction with water.
Equation and observations

A

2Na(s)+ 2H2O(l) → 2NaOH(aq) + H2(g)
Reacts vigorously
forms a ball
fizzing

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3
Q

Mg reaction with water and steam
Equation and observations

A

Mg(s) + 2H2O(l) → Mg(OH)2(aq) + H2(g)
Bright white light
White solid
reacts faster with steam: Mg(s) + H2O(l) → MgO(s) + H2(g)

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4
Q

Na reaction with oxygen
Equations and observations

A

4Na (s) + O2 (g) → 2Na2O (s)
vigorous reaction
bright yellow flame
white solid

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5
Q

Mg reaction with oxygen
Equations and observations

A

2Mg (s) + O2 (g) → 2MgO (s)
vigorous reaction
bright white flame
white solid
more intense if lowered into jar of oxygen

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6
Q

Al reaction with oxygen
Equations and observations
Why does it seem to be unreactive?

A

4Al (s) + 3O2 (g) → 2Al2O3 (s)
fast reaction
powdered Al
bright white flame
white powder
always coated in a strongly bonded layer of oxide to prevent further reaction so seems unreactive

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7
Q

Si reaction with oxygen
Equations and observations

A

Si (s) + O2 (g)→ SiO2 (s)
slow reaction
powdered Si burns if strongly heated in oxygen
bright white sparkles
white powder

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8
Q

P reaction with oxygen
Equations and observations

A

4P (s) + 5O2 (g) → P4O10 (s)
White P is spontaneous combustion
white flame
white smoke
white solid
Red P must be heated before reaction

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9
Q

S reaction with oxygen
Equations and observations

A

S (s) + O2 (g) → SO2 (g)
gentle reaction
blue flame
For SO3 to form, a catalyst must be used and the reaction must take place at a very high temperature
The equation for this reaction is:
2S (s) + 3O2 (g) → 2SO3 (g)

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10
Q

Oxides of Na, Mg, Al
structure and bonding

A

giant ionic lattice
strong electrostatic forces of attraction between oppositely charged ions
spreads throughout compound
gives it a high melting point
lots of energy required to overcome

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11
Q

Bonding in Al2O3

A

ionic/covalent
metal + non-metal
due to it being a small ion with a large positive charge
the Al+3 ion can polarize electron charge from O-2 ion. That can give the bond some covalent character.

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12
Q

SiO2
structure and bonding

A

macromolecular
many strong covalent bonds spread throughout structure
a lot of energy required to break covalent bonds

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13
Q

oxides of P,S
structure and bonding

A

simple molecular
weak wan der waals

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14
Q

trends in melting points for oxides

A

Na2O < MgO > Al2O3 >
SiO2 > P4O10 > SO3 > SO2

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15
Q

Na2O reaction with water
equations, ionic , PH

A

Na2O + H2O → 2NaOH
Na2O + H2O → 2Na+ + 2OH-
PH 13-14
strongly alkaline

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16
Q

MgO reaction with water
equations, ionic , PH

A

MgO + H2O → Mg(OH)2
MgO + H2O → Mg(2+) + 2OH-
PH 9
weakly alkaline

17
Q

Al2O3, SiO2 reaction with water

A

insoluble
al— amphoteric
Si— acidic

18
Q

P4O10 reaction with water
equations, ionic , PH

A

P4O10 + 6H2O → 4H3PO4
P4O10 + 6H2O → 12H+ + 4PO3