Production of Materials, Acidic Environment. Flashcards

0
Q

A reaction that displaces Hydrogen involves the combination of an active metal with an acid. What equation represents the products of a reaction between Magnesium and Hydrochloric Acid?

A) MgCl + H2
B) Mg2Cl + H
C) MgCl + H
D) MgCl2 + H2

A

D

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1
Q

The following equation represents the combustion of Methane in the presence of an excess of Oxygen: aCH4 + bO2 –> cCO2 +dH2O
After it has been balanced, what is the correct molar ratio?
a b c d
A) 1 2 1 2
B) 2 1 2 1
C) 1 2 1 1
D) 1 2 2 1

A

A

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2
Q

What is the best ‘word’ description of the equation below?
HCl + NaOH –> NaCl + H2O

A) Acid + Base –> Salt + Water
B) Active Metal + Base –> Salt + Water
C) Base + Acid –> Nonmetal Compound + Water
D) Acid + Base –> Natrium Chloride + Water

A

A

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3
Q

What is the most correct answer for the following reaction below?
Al + O2 –>

A) Al2O3
B) AlO3
C) Al(OH)3
D) Al2O3

A

D

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4
Q
What are the most likely substances to fill the spaces of the reaction below?
x + CaCO3 --> CaCl2 + y + H2O
      x           y
A) 3HCl     CaCO
B) H2Cl     CaO
C) 2HCl     CO2
D) 2HClO  CO2
A

C

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5
Q
The below process is used in the oil industry. What are the most likely names for the two products?
Pentene -catalyst-> x + y
          x          y
A) Pentane  Hexane
B) Ethane    Propane
C) Ethene    Propene
D) Propene  Ethane
A

C

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6
Q

Which of the following molecules would be most reactive?

A) 2- Methylbutane
B) 2,3-Dimethylhexane
C) Methane
D) 2-Butene

A

D

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7
Q

Substance Y produced in the below reaction would be?
CH3–CH=CH2 + H2O -H2SO4 -Catalyst-> Y

A) 2-Propanol
B) 1-Hydratedpropane
C) 1,2-Propanol
D) Propane

A

A

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8
Q
The formula below is for a general long chain alkane. Which of the following substances could be used to construct it?
(-CH2-)n
A) (Ethene)1/2n
B) (Butene)n
C) (Ethene)n
D) (Polypropylene)1/2n
A

A

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9
Q

A property common to almost all polymers would be that they

A) Are all low density
B) Have a natural rigidity
C) Are good thermal and electrical insulators
D) Are chemically active

A

C

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10
Q

During the manufacture of Polyethene, swapping one of the Hydrogen in Polyethene with Chlorine results in

A) Increased thermal resistance
B) Decreases the electrical resistance
C) Forms a more rigid plastic
D) Makes it more resistant to attack

A

C

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11
Q
The table gives the heat of combustion in kJ.g-1 for a number of different fuels.
           fuel         Heat of Combustion (kJ.g-1)
Methanol           22.7 
Ethanol              29.6
Propanol            33.6
Octane               47.8
The heat of combustion in kJ.mol-1 for one of the fuels was calculated as 2016 kJ.mol-1.
What was the fuel?
A) Methanol
B) Ethanol
C) Propanol
D) Octane
A

C

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12
Q
A student tried to determine the molar heat of combustion of propanol using 200g of water in a can with a themometer in it, and a burner underneath the can containing 1-Propanol.
The following results were obtained:
Mass of 1-Propanol burnt= 0.60g
Mass of water heated= 200g
Initial temperature of water= 21.0 'C
The molar heat of combustion of 1-Propanol is 2021 kJ.mol-1. Assuming no heat loss, what would be the final temperature of the water?
A) 24.2'C
B) 29.1'C
C) 45.2'C
D) 48.4'C
A

C

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13
Q
Plutonium -241 is an unstable isotope and quickly decays to another more stable element by emitting a "beta" particle. The new element would be:
A) americium-242
B) americium-241
C) plutonium-242
D) neptunium-241
A

B

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14
Q

Sodium azide is used in automobile airbags to provide a source of nitrogen gas for rapid inflation in an accident. The equation shows the production of nitrogen gas from sodium azide.
2NaN3(s) –> 2Na(s) + 3N2(g)
What mass of sodium azide will produce 40 L of N2 at 100 kPa and 0’C?
A) 70 g
B) 76 g
C) 114 g
D) 172 g

A

B

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15
Q

Phosgene is prepared from the equilibrium reaction of carbon monoxide and chlorine in the presence of a catalyst:
CO(g) + Cl2(g) COCl2(g) delta H= -9.93 kJ.mol-1
Which of the following sets of conditions would produce the highest yield of phosgene?
A) High temperature, high pressure
B) Low temperature, low pressure
C) Low temperature, high pressure
D) High temperature, low pressure

A

C

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16
Q

The ion HCO3- is commonly found in blood and is part of the “buffering” system that maintains a stable pH in the body. Acidosis is a condition often found in older people where the pH slips below 7 and can disrupt many natural functions. If the buffering system is working properly and the pH does drop below 7, which of the following reactions is most likely to happen?
A) The HCO3- ion will react to form H2CO3(aq)
B) The HCO3- ion will react to form O2 + H2O
C) The HCO3- ion changes to CO3*2-
D) The HCO3- ion soaks up the excess CO2 floating in the blood

A

A

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17
Q

What features of the molecular structure of ethanol account for its extensive use as a solvent? Include a diagram in your answer.

A

Includes:

  • The dispersion forces between the C2H5 end of the molecule account for its use as a non-polar solvent.
  • Unbonded electrons on the OH end of the molecule, account for its use as a polar solvent.
  • In diagram, shows unbonded electrons on O as lewis dots. And includes delta positive and delta negative on OH end. (Permanent dipole established).
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18
Q

Name and describe the chemistry of a radioisotope in the following:
-Industry

A

Includes:

  • Americium-241 is used for smoke alarms.
  • The half life of the radioisotope, and what it emits. (432 years).
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19
Q

In the margarine industry, alkenes are often hydrogenated to convert unsaturated oils into solid fats that have a greater proportion of saturated molecules. Using ethene as an example, write an equation for this reaction and state the type of reaction this represents.

A

Addition Reaction:

C2H4(g) + H2(g) –> C2H6(l)

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20
Q

Outline the procedure you would use to prepare a standard solution of sodium hydrogen carbonate from solid sodium hydrogen carbonate.

A

Includes:

  • The equipment used; Volumetric flask, pipette, Distilled water, volumetric scale.
  • Procedure; Weight the mass of solid sodium hydrogen carbonate solution and record. Rinse Volumetric flask, and pipette in distilled water. Add solid sodium hydrogen carbonate. Add distilled water through pipette into volumetric flask until it reaches the line on the volumetric flask.
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21
Q

Calculate the mass of solid sodium hydrogen carbonate required to make 250 mL of 0.12 mol.L-1 solution.

A
n= cv
n= 0.12 x 0.250
n= 0.03 mol
m= nM
m= 0.03 x 84.00
m= 2.52 g
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22
Q

What volume of 0.005 mol.L-1 KOH is required to neutralise 15 mL of 0.0005 mol.L-1 solution of H2SO4?

A

3 mL

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23
Q

How can a monomer be altered to produce stiffer or more rigid polymers?

A

Includes:
-The more alkyl groups or extra atoms that can be substituted for the H atoms the “stiffer” the plastic. I.e. C2H3Cl produces a more rigid polymer than C2H4.

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24
Q

Describe how long carbon chain molecules (15-25 atoms) can be turned into ethene molecules. Give an example and include the formula.

A

Includes:
-They are changed by the process of “cracking” with the help of a catalyst.
C15H32 -catalyst-> C10H22 + C5H10 -Catalyst-> C2H4 + C3H6

25
Q

Briefly describe where crude oil comes form.

A

Includes:
-Crude oil is stored underground structures called anticlines and removed by drilling down to the trapped fluids and gases.

26
Q

Write a balanced equation for the complete combustion in oxygen of ethanol.

A

Includes:

-CH3CH2OH + 3O2 –> 2CO2 + 3H2O

27
Q

Write a balanced equation for the below reaction:

Nitrogen + Hydrogen Ammonia

A

N2 + 3H2 –> 2NH3

28
Q

If 6 moles of nitrogen react with excess of hydrogen, how many moles of ammonia are produced?

A

12 moles of NH3 is needed.

29
Q

What is a covalent bond? Give two examples of covalent molecules.

A

Includes:
-A bond between non-metals where the electrons are shared across the bond to achieve a stable electron configuration. i.e. HCl, O2, H2O, CH4.

31
Q

Write, complete and balance the equation of a lead-acid battery.

A

PbO2 + 2H2SO4 + Pb –> 2PbSO4 + 2H2O

32
Q

Write, complete and balance the equation of absorption of carbon dioxide into the oceans to reduce the greenhouse gas concentrations in the atmosphere.

A

CO2 + H2O H2CO3

33
Q

From your studies, describe some reactions that display the differing reactivity of an alkane compared to an alkene. Write equations to help you explain.

A

Includes:

-The reactions of ethene with bromine water, and ethane in the presence of light.

34
Q

Complete and balance the following equations.

          * * Please note that you may not have come across these equations yet, so use the index in your textbook to search for them. a. (i)   Mg   +   \_\_\_\_\_\_\_\_\_\_\_--> MgO
(ii) \_\_\_\_\_\_\_\_\_\_   +   HCl --> ZnCl2   +   \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
(iii) \_\_\_\_\_\_\_\_\_\_\_+   \_\_\_\_\_\_\_\_\_\_\_ --> Al2(SO4)3   +   H2 b. (i)   Zn   +   Cu(NO3)2 --> \_\_\_\_\_\_\_\_\_\_\_\_\_\_   +   \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
(ii) Pb(NO3)2   +   NaCl --> \_\_\_\_\_\_\_\_\_\_\_\_\_\_   +   \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
(iii) nitric acid +   copper (II) --> \_\_\_\_\_\_\_\_\_\_\_\_\_\_   + \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_hydroxide
A

Includes:
-1a. (i) 2Mg + O2 –> 2MgO

(ii) Zn +  2HCl	 -->	ZnCl2   +   H2
(iii) 2Al + 3H2SO4 --> Al2(SO4)3   +   3H2 b. (i)   Zn   +   Cu(NO3)2	 --> Zn(NO3)2 +  Cu (ii) Pb(NO3)   +   2NaCl --> PbCl2 +  2NaNO3
(iii) 2HNO3 +  Cu(OH)2 --> Cu(NO3)2 +  2H2O
35
Q

The reason many scientists are looking for alternative sources of hydrocarbons is that:

A) the new sources will be cheaper
B) the new sources will supply stronger, more stable molecules
C) the current supplies of crude oil are predicted to run out in a few decades
D) cellulose is an easier product to catalytically crack than crude oil derivatives

A

C

36
Q

10 drops of dilute bromine water were added to two chemicals, labelled X and Y. One chemical was 2-pentene and the other was pentane. The following observations were recorded by four different students.

Student Chemical X Chemical Y
1 No reaction No reaction
2 Decolourisation Decolourisation
3 Decolourisation No reaction
4 No reaction Decolourisation

Which student/s obtained results that could be correct?

A) Students 1
B) Students 1 and 2
C) Students 2 and 4
D) Student 4

Another student was dissatisfied with the results obtained by the four students and wished to improve the reliability of the results. How could this be done?

A) By asking the students to be more careful.
B) By carrying out the experiment under a variety of conditions.
C) By having each student repeat the experiment a number of times.
D) By making sure that the experiment is carried out under the same conditions.

A

D

C

37
Q

Which statement is true for the following reaction?
Zn(s) + CuSO4(aq) –> ZnSO4(aq) + Cu(s)

A) Zinc is reduced and copper ions are the oxidant.
B) Copper ions are reduced and zinc is the reductant.
C) Sulfate ions are oxidised and zinc is the oxidant.
D) Zinc ions are the reduction product and copper is the reductant.

A

B

38
Q

Ethanol can be converted to ethene. What is this type of reaction called?

A) Esterification
B) Dehydration
C) Hydration
D) Polymerisation

A

D

39
Q

Which of the following is a major component of biomass?

A) Cellulose
B) Ethanol
C) Natural Gas
D) Oil

A

A

40
Q

Which equation best represents the catalytic cracking of a petroleum fraction?

A) C16H32(l) -Al2O3-> C16H32(g)
B) nC2H4(g) –> -(CH2-CH20)-n (s)
C) C16H32(l) -Al2O3-> C7H16(l) + 3CH2H4(g) + C3H6(g)
D) C7H16(l) + 3C2H4(g) + C3H6(g) -Al2O3-> C16H32(l)

A

C

41
Q

Which conditions would be best for the fermentation of sugars by yeast?

A) Low oxygen concentration and a temperature between 25 and 35 degrees celcius.
B) High oxygen concentration and a temperature between 25 and 35 degrees celcius.
C) Low oxygen concentration and a temperature between 45 and 60 degrees celcius.
D) High oxygen concentration and a temperature between 45 and 60 degrees celcius.

A

A

42
Q

What is the catalyst for the conversion of ethanol to ethene?

A) NaOH
B) H2SO4
C) HNO3
D) Pt

A

B

43
Q

Which of the following is a transuranic element?

A) Caesium
B) Cerium
C) Chromium
D) Curium

A

D

44
Q

Why is research into synthetic biopolymers attracting great interest?

A) They can decompose more easily than traditional synthetic polymers.
B) They can be produced more cheaply than traditional synthetic polymers.
C) They have superior physical properties compared to traditional synthetic polymers.
D) They have superior chemical properties compared to traditional synthetic polymers.

A

A

45
Q

The following results were obtained with four metals, x, y, z, Pb being attached to pairs and the voltage was recorded:

Negative terminal Positive Terminal Voltage
Pb x 0.35
y Pb 1.10
z Pb 2.60

What is the order of increasing ease of oxidation of the metals?

A) z, y, Pb, x
B) Pb, x, y , z
C) x, y, Pb, z
D) x, Pb, y, z

A

D

46
Q

Evaluate the use potential use of the biopolymer Polyhydroxybutyrate (PHB).

A

Includes:

  • PHB is transparent, brittle, water-proof and lightweight, and would be suitable for bottles and other containers.
  • Being a biopolymer, it is biodegradable; therefore it can be thrown out or buried without environmental implications.
  • Since PHB is non-toxic and can decompose in the body, it might also be used as medical sutures or for stabilisation of healing bones.
  • Therefore PHB has many excellent uses or potential uses that are all seen as advantages, with the cost of production being the only negative for its widespread use.
47
Q

Martin prepared ethanol by two different methods, the hydration of ethene and by fermentation.
A) Write balanced chemical equations to describe the formation of ethanol by both methods.
B) Compare the roles of sulfuric acid and yeast in these two reactions.

A

A)
- C2H4(l) + H2O(l) -dilute H2SO4 catalyst-> CH3CH2OH(l)
- C6H12O6(aq) -yeast-> 2CH3CH2OH(aq) + 2CO2(g)
B)
Sulfuric acid and Yeast:
-Similarities:
*Necessary for the reaction to proceed, but is not consumed by the reaction.
-Differences:
*H2SO4 aids in the dehydration reaction.
*Yeast provides the biological enzymes necessary for the fermentation reaction.

48
Q

Discuss the use of ethanol as a fuel.

A

Includes:
- Ethanol is non-corrosive, leading to cleaner fuel systems, renewable, 10% ethanol in petrol used without modification of engines but not more than 20% combusts more fully, reduces pollution and greenhouse gases.

49
Q

Ethanol has many uses as a solvent because it can dissolve:

A) Ionic compounds by forming hydrogen bonds between the positive and negative ions and its CH3-CH2 functional group.
B) Ionic compounds by forming dispersion forces between the positive and negative ions and its OH functional group.
C) Molecular compounds by forming hydrogen bonds between the neutral molecules and its OH functional group.
D) Molecular compounds by forming dispersion forces between the neutral molecules and its CH3-CH2 functional group.

A

D

50
Q

A radioisotope must have the following characteristics to be used to diagnose diseases in the body by being injected into the blood system.

A) It must emit alpha radiation and form compounds that are soluble in water.
B) It must emit beta radiation and form compounds that are soluble in water.
C) It must emit beta radiation and form compounds that are insoluble in water.
D) It must emit gamma radiation and form compounds that are soluble in water.

A

D

51
Q

Daniel uses a sodium hydroxide solution of known concentration to determine the concentration of acetic acid in vinegar. Which of the following would be a suitable indicator for this titration?

A) Bromothymol Blue
B) Litmus
C) Methyl Orange
D) Phenophthalein

A

D

52
Q

Melaine discovered that when a volume of soda water was decarbonated there was a mass loss of 0.076g. What volume would be occupied by this mass of gas at a temperature of 25 degrees celcius and a pressure of 100kPa?

A) 42.8mL
B) 157mL
C) 1880mL
D) 14300mL

A

A

53
Q

Sarah wished to prepare a solution whose pH would not be changed by the addition of small amounts of strong acids or bases. Which compounds would be suitable for Sarah to use to make this solution?

A) Sulfuric acid and Potassium sulfate
B) Nitric acid and Ammonium nitrate
C) Hydrochloric acid and sodium hydroxide
D) Acetic acid and potassium nitrate

A

D

54
Q

Which of the following is a transuranic element?

A) Caesium
B) Cerium
C) Chromium
D) Curium

A

D

55
Q

Why is research into synthetic biopolymers attracting great interest?

A) They decompose more easily than traditional synthetic polymers.
B) They can be produced more cheaply than traditional synthetic polymers.
C) They have superior physical properties compared to traditional synthetic polymers.
D) They have superior chemical properties compared to traditional synthetic polymers.

A

A

56
Q

The heat of combustion of butan-1-ol is 2676 kj mol-1. What is the value of the heat of combustion in kj g-1?

A) 30.41
B) 36.10
C) 44.60
D) 47.79

A

B

57
Q

IN 1884, Svante Arrhenius proposed a definition for acids. His definition was soon accepted as superior to that put forward by earlier chemists. Why was Arrhenius’ definition seen as a major improvement?

A) It explained why some acids do not contain oxygen.
B) It showed how the solvent can affect the strength of an acid.
C) It showed the relationship between pH and the concentration of H+ ions.
D) It could be used to explain why some acids are strong and others are weak.

A

D

58
Q

Daniel uses a sodium hydroxide solution of known concentration to determine the concentration of acetic acid in vinegar. Which of the following would be a suitable indicator for this titration?

A) Bromothymol Blue
B) Litmus
C) Methyl Orange
D) Phenolphthalein

A

D

59
Q

Melanie discovered that when a volume of soda water was decarbonated there was a mass loss of 0.076 g. What volume would be occupied by this mass of gas at a temperature of 25 degrees Celsius and a pressure of 100 kpa?

A) 42.8 mL
B) 157 mL
C) 1880 mL
D) 14300 mL

A

A

60
Q

Show how major advances in the understanding and development of polymers or biopolymers have changed the direction or nature of scientific thinking.

A

Includes:

-