(Prelim) Exp 2&3 Post-LAB Flashcards

1
Q

It is the range of temperature at which the solid phase changes to liquid.

A

Melting Point

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2
Q

It is the temperature at which the thermal motion of the molecules is just enough to break down the lattice structure of the crystal

A

Melting Point

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3
Q

have sharp melting point because of the symmetry in structure and
in strength of bonds.

A

Crystal solids

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3
Q

have sharp melting point and this physical property can be used to determine purity or presence of impurities.

A

Pure compounds

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3
Q

It provides a means of testing for the identity of two solids by examination of the melting
point behavior of a mechanical mixture of the two

A

Mixed melting points method

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4
Q

It is valuable at certain points for the identification of unknowns.

A

Mixed melting points method

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5
Q

the larger the molecule, the higher the melting point.

A

For alkanes

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5
Q

the more ordered the molecule, the more energy is required to break the intermolecular
forces holding the molecules together.

A

For solids

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6
Q

have a lower trend in melting points than even-numbered alkanes because even-
numbered pack well in the solid phase, forming a well-organized structure.

A

Odd number alkanes

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6
Q

have higher melting points compared to non-planar hydrocarbons with similar molecular weights

A

Flat shape aromatic compounds

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7
Q

In the periodic table, melting point decreases

A

from center going to the sides (left and right); decrease from top to bottom.

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8
Q

have very high melting points

A

Ionic compounds

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9
Q

Presence of polar and hydrogen-bonding groups on organic compounds generally leads to _____________

A

higher melting points

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10
Q

Oxalic acid

A

MW: 90
MP: 102

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11
Q

Naphthalene

A

MW:128
MP: 80.26

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12
Q

Benzoic acid

A

MW: 122
MP: 122

13
Q

Malic acid

A

MW: 134
MP: 130

14
Q

Urea

A

MW: 60
MP: 133

15
Q

Salicylic acid

A

MW: 138
MP: 158.6

16
Q

Succinic acid

A

MW: 118
MP: 184

17
Q

Apparatus used to measure melting point:

A
  • Thomas-Hoover Uni-melt melting point apparatus
  • Thiele tube melting point apparatus
  • Fisher-johns melting point apparatus
  • Nalge-axelrod melting point apparatus
  • Stuart melting point apparatus SMP10
17
Q

p-amino benzoic acid

A

MW: 137
MP: 187

18
Q

It is the temperature in which the vapor pressure is equal to the atmospheric pressure.

A

Boiling Point

18
Q

Sodium benzoate

A

MW: 144
MP: 410

19
Q

It can give information about their physical properties and structural characteristics of
compounds.

A

Boiling Point

20
Q

It can also be used identify and characterize compounds.

A

Boiling Point

21
Q

Just like melting point, the relative strength of intermolecular forces can affect ________

A

boiling point of compounds

21
Q

It is dependent on the kinetic energy of particles and varies with the surrounding
atmospheric pressure

A

Boiling Point

22
Q

Presence of polar and hydroxyl groups can increase ______________

A

boiling point of compounds.

23
Q

As the length of ________ increases, the boiling point also increases

A

carbon chain

24
Q

Increase in the length of the carbon chain increases surface area of the compound while branching of molecules __________ the surface area.

A

decreases

25
Q

_________________ boil higher than secondary and tertiary alcohols.

A

Primary alcohols

26
Q

Acetic acid

A

MW: 60
BP: 118

27
Q

N-hexane

A

MW: 86
BP: 68.6

28
Q

N-pentane

A

MW: 72
BP: 36.1

29
Q

N-butyl alcohol

A

MW: 74
BP: 117.7

30
Q

Sec-butyl alcohol

A

MW: 144
BP: 112

31
Q

Tert-butyl alcohol

A

MW: 74
BP: 82.2