Precipitation and Complexation Methods of Analysis Flashcards
require the formation of relatively
insoluble substances or precipitates
to cause the reactions to go to
completion; solution must be titrated
Volumetric Precipitimetry
Cessation of precipitation or the
appearance of turbidity
Determination of End Point
used in both direct and residual titration
Ferric Ammonium Sulfate TS (FAS/Ferric Alum)
employs standard ammonium
thiocyanate solution
Ferric Ammonium Sulfate
thiocyanate reacts with___or___ ions
present to form white precipitate of
silver or mercuric thiocyanate
Hg or Ag
thiocyanate reacts with Hg or Ag ions
present to form white precipitate of
______ or ___________
silver or mercuric thiocyanate
the thiocyanate ions reacts with
ferric ammonium sulfate to form
a ______________________
red ferric thiocyanate
forms a red precipitate of silver chromate which is seen against the background of white silver chloride
Potassium Chromate TS
used in the analyses of halides by direct titration with silver nitrate solution
Adsorption Indicators