Portland cement Flashcards

1
Q

glue that bonds aggregate together to make concrete

A

cement paste (cement + water)

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2
Q

cement paste and sand

A

mortar

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3
Q

cement + water + sand + gravel

A

concrete

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4
Q

process to make portland cement

A

crushing and grinding of raw materials, heat and melt in kiln that forms cement clinker, add gypsum to clinker and pulverize to fine powder

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5
Q

chemical composition of PC

A

tricalcium silicate, dicalcium silicate, tricalcium aluminate, and tetracalcium aluminoferrite

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6
Q

How is fineness important when making PC

A

smaller particles have more surface area to react with water, fineness controls the rate of hydration (heat and strength game)

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7
Q

measures air permeability against known standard material

A

Blaine test

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8
Q

measures sedimentation rate suspended in kerosene

A

Wagner Turbidimeter

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9
Q

specific gravity of cement (w/o air voids)

A

3.15

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10
Q

chemical reaction of cement w water

A

hydration

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11
Q

dominates early stage of hydration

A

through-solution

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12
Q

solid state reaction at cement surface

A

topochemical

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13
Q

Hydration rate: aluminates > silicates

A

needs balance

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14
Q

Hydration of C3S & C2S

A

makes paste strong

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15
Q

Primary Chemical Reaction Chemical reactions that harden cement paste

A

Fast in the beginning but is long term (decades in dams), Causes heat, which can be a problem if there’s too much

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16
Q

Voids in hydration space

A

interlayer hydration space, capillary voids, trapped voids, entrained air

17
Q

space between atomic layers, shrinkage if humidity is less than 11%

A

interlayer hydration space

18
Q

w/c too high, decrease strength and increased permeability

A

capillary voids

19
Q

large pockets caused by handling, decrease strength and increase permeability

A

trapped voids

20
Q

microscopic bubbles caused by admixtures, increased durability

A

entrained air

21
Q

change from plastic state to solid state

A

stiffening

22
Q

premature stiffening within a few minutes

A

False Set

23
Q

sets that cannot be fixed

A

quick and flash sets

24
Q

Ability for concrete to retain volume after setting

A

Soundness

25
Q

Most important property of hydrating cement

A

water-cement ratio

26
Q

w/c need for hydration

A

0.4

27
Q

Pros and cons of adding extra water to cement?

A

improves workability but also causes voids

28
Q

types of PC

A
I. Normal
II. Moderate Sulfate Resistance
III. High Early Strength
IV Low Heat of Hydration
V. High Sulfate Resistance
29
Q

produce tiny, dispersed air bubbles into the concrete, causes cracking and internal stress, this prevents this from happening

A

Air Entrainers

30
Q

Air Entrainers decrease strength by 20% but can be compensated with lower w/c ratio

A

true

31
Q

Three ways to use water reducers

A
  1. ) improve workability using same w/c ratio
  2. ) increase strength using lower w/c ratio
  3. ) reduce cost at same w/c ratio by reducing both water and cement
32
Q

delay or retard initial set (increase set time), may reduce early strength, usually doesn’t reduce final set time, long haul time

A

Retarders

33
Q

have the ability to stop and reactivate the hydration process of concrete

A

Hydration Controllers

34
Q

2 parts to hydration controllers

A

stabilizer and activator

35
Q

speed up initial and final set times

A

Accelerators

36
Q

What are accelerators used for?

A

increase rate of strength gain, reduce the amount of time before finishing operations begin, reduce curing time, plug leaks under hydraulic pressure efficiently

37
Q

Most common accelerator

A

calcium chloride

38
Q

most common supplementary cementitious Materials

A

Fly Ash

39
Q

Classes of Fly Ash

A

N, F, and C