Polymers And Amino Acids Flashcards
Additional polymer
Long chain made from many monomers and no product is formed
Condensation polymer
In a condensation reaction 2 molecules join to form a larger molecule with a small molecule such as hcl or h2o being released
Polyester
Alcohol + carboxylic acid react
Ester functional group is formed and water is made
Need to know polyester
Terylene
Ethane-1-2-diol and benzene-1-4-dicarboxylic acid
Uses - carpets clothes
Polyamides
When as amine and a carboxylic acid react - amide functional group formed
Need to know polyamide
Nylon 6,6
1,6-diamino hexene and hexane-1,6-dicarboxylic acid
Uses - fibres in clothing
Need to know example polyamide
Kevlar
Benzene-1,4-diamine and benzene-1,4- dicarboxylic acid
Uses- used in manufacture of body armour and crash helmets
Additional polymers biodegradable
Have non polar c-c bonds cannot be hydrolysed
Burn or incinerated - environmental issues
Condensation polymers biodegrade
Are biodegradable
Can be hydrolysed in acid/basic conditions
Amino acids in neutral ph
Zwitterion
N gains a proton positive charge
Oh on carboxylic acid loses a proton so negative charge
Amino acids in acidic and alkaline conditions.
In acidic conditions amine/base accepts a proton
In alkaline conditions carboxylic acid is deprotonated
Enzymes and optical isomers
Specific to 1 isomers- stereospecific
Anti cancer drugs
Cisplatin
Binds to dna in cancerous cells so dna cannot unwind
Can bind to dna in healthy cells - can be targeted straight to cancer cells
Unwanted side effects - can be given in minimal amounts
Replaces 2 chloride ligands with a nitrogen from 2 adjacent guanine bases