Polymers Flashcards

1
Q

Nylon - 6,6 monomer

A

Hexamethylene diamine and adipic acid

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2
Q

Nylon - 6,6 polymer type

A

Condensation polymer

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3
Q

polythene polymer type

A

Addition polymer

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4
Q

Rayon

A

Cellulose acetate

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5
Q

Classification based on source

A

Natural, semi-synthetic, synthetic

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6
Q

Natural polymers

A

Cellulose, rubber, starch, resins, proteins

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7
Q

Semi-synthetic polymers

A

Rayon, cellulose nitrate, cellulose xanthate

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8
Q

Synthetic polymer

A

Polythene, Nylon - 6,6, Buna-S

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9
Q

Synthetic rubber

A

Buna-S

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10
Q

Classification based on structure

A

Linear, branched chain, cross linked/network

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11
Q

Linear polymers

A

High density polythene, PVC, polyester

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12
Q

Branched chain polymer

A

Low density polythene

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13
Q

Cross linked/network polymers

A

Bakelite, melamine

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14
Q

Bonding in cross linked polymers

A

Strong covalent bonds

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15
Q

Cross linked polymers are formed from

A

bi-functional and tri-functional monomers

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16
Q

Classification based on mode of polymerisation

A

Addition polymers (homo+co), Condensation polymers

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17
Q

Buna-S

A

Styrene + 1,3-Butadiene

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18
Q

Homopolymers

A

Polythene

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19
Q

Copolymers

A

Buna-S, Buna-N

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20
Q

Condensation polymers

A

terylene(dacron), nylon-6,6, nylon-6

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21
Q

Classification based on molecular forces

A

Elastomers, fibers, thermoplastic polymers, thermosetting polymers

22
Q

Elastomers

A

Weak van der Wall forces (Buna-S, Buna-N, neoprene)

23
Q

Fibers

A

Strong hydrogen bonding, crystalline (polyamide, polyester)

24
Q

Polyamide

25
Polyester
Terylene/dacron
26
Thermoplastic
Intermolecular forces are in between elastomers and fibers, no cross linking, capable of softening on heating and hardening on cooling (polythene, polystyrene, polyvinyls)
27
Thermosetting
Heavily branched and cross linked, infusible 3D network solid, cannot be reused (Bakelite, urea formaldehyde resin)
28
Classification based on growth of polymer chain
Addition/Chain growth polymer, Condensation/step growth polymer
29
Addition/chain growth polymers
LDP, HDP, PTFE(Teflon), Polyacrylonitrile(PAN)
30
Condensation/step growth Polymers
Terylene/dacron(polyester), Nylons(polyamides), Novolac, Bakelite (Phenol+formaldehyde), Melamine(Melamine+formaldehyde)
31
Copolymerisation
Styrene butadiene rubber (SBR is more flexible than polybutadiene and tougher than polystyrene(homopolymers))
32
Natural rubber
Linear hydrocarbon polymer of isoprene (cis-1,4-polyisoprene)
33
Natural rubber is soluble in
Non polar solvent
34
Vulcanization of natural rubber
Rubber+ sulphur(5%) at 373 to 415K, Sulphur froms cross links at double bond sites, rubber becomes more hard and flexible
35
Synthetic rubber
Neoprene, Buna-N
36
Neoprene
Chloroprene
37
Buna-N
1,3-butadiene+acrylonitrile
38
Molecular mass of polymers
Always expresed as an average
39
Molecular mass of natural polymers (proteins)
Molecular masses are singular and not expressed as average
40
Biodegradable polymers
Nylon-2-Nylon-6, Polybetahydroxybutyrate-co-p-hydroxyvalerate(PHBV)
41
Nylon-2-Nylon-6
Glycine+Amino caproic acid
42
PHBV
3-Hydroxybutanoic acid + 3-Hydroxypentanoic acid
43
Glyptal
Ethylene glycol+Phthalic acid
44
Orlon/Acrilan
Vinyl cyanide (polyacrylonitrile)
45
Terylene/dacron/mylar
Ethane-1,2-diol + Terephthalic acid
46
Nylon-6
Caprolactum
47
Gutta-Percha
Trans- polyisoprene, non elastic, non crystalline
48
Nylon-6-Nylon-10
Hexamethylene diamine + Sebacic acid
49
Dynel
Copolymer of acrylonitrile and vinyl chloride
50
Thiokol
1,2-dichloroethane