Polymers Flashcards

1
Q

What are plastics/polymers?

A
  • low density, low strength, low stiffness and electrical and thermal insulating properties. also chemical insulating
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Plastics Greek word

A

plastikos meaning it ca be molded and shaped

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Early Polymers

A

natural organic materials - cellulose.

synthetic polymer - phenol formaldehyde 1906

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Modern Polymers

A

1920s, polymers were produced using petroleum products (ethylene)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Structure of Polymers

A

A monomer is the basic building block.
Organic compounds in which carbon atoms are attached covalently.
Repeating monomers created through polymerization

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Polymerization

A

Thermoplastic and Thermosets

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Thermoplastics

A

Linear - have a linear bonding structure

Branched - have branched structure hence have higher strength and lower densitiy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Thermosets

A

Crosslinked - adjacent chains linked covalently. Increases strength and dimensional stability
Networked polymers - have three or more active covalent bonds for improved strength

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Crystallinity

A

Polymers can be crystalline or amorphous
As crystallinity increases, polymers become stiffer, harder and less ductile
Crystallinity can be imparted by processing but never 100%
Amorphous structures can be transparent and as crystallinity increases opaqueness increases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Glass Transition Temperature

A

As temperature increases amorphous polymers undergo a change

Low Temp - hard, glass, brittle
High Temp - Rubbery, leathery

Transition occurs at Glass transition Temp.
Crosslinking makes this temperature less defined

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Thermoplastics

A

strength determined by secondary bonds
increasing temp, causes bonds to break and can be shaped

Upon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Thermoplastics

A

Upon cooling strength determined by secondary bonds
increasing temp, causes bonds to break and can be shaped

Upon cooling the original strength and hardness returns. Can cause thermal aging.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Thermoplastics

A

strength determined by secondary bonds
increasing temp, causes bonds to break and can be shaped

Upon cooling the original strength and hardness returns. Can cause thermal aging.

Constant load applied causes the polymer to stretch at a high strain rate and elongates over time.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Thermoplastic Examples

A

Acetals
Acrylics
Polycarbonates
PVC

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Acetals

A

Good strength, stiffness, chemical resistances.

App - Bearings, cams, rollers, Delrin

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Acrylics

A

possess moderate strength, good optical properties.

App - Lighted signs, skylights,plexiglass

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Polycarbonate

A

Versatile, with great impact resistance.

App : Windshields, Safety Helmets (Lexan)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

PVC (Polyvinyl Carbonate)

A

inexpsnive, water resistant, not suitable for high temps

Apps: Pipes, conduits, flexible hose (tygon)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Thermosets

A

Long chained molecules, crosslinked in a strong covalent bond.
Cross linking process is irreversible
Strength is not affected by temperature or rate of deformation. High temp will cause burning
Have bettern mechanical properties and dimensionally stable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Thermoset example

A

Aminos
Phenolics
Polysters

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Aminos

A

Rigid, hard and resistant to abrasion and creep.

App: Countertopps, appliance housing (Melamine)

22
Q

Phenolics

A

High Resistance to heat, waer and chemicals
App: handles, knocs, conectors
(Bakelite)

23
Q

Polysters

A

Good mechanical properties and electrical properties. Used with fibres or available as castin resisn.
App: Clothing, textiles, swimming pools, boats (cool max)

24
Q

Elastomers (ie rubber)

A

A polymer capable of recovering substantially in size and shape after a load as been removed
properties: low glass transition temp, large deformations without rupture, soft, low elastic modulus

highly linked structure
good in vibration insulation, non skid surfaces and abrasion resistant.

maybe crosslinked for added strength (vulcanisation : sulfur added at high temps)

25
Elastomer examples
Natural rubber Synthetic rubber Silicones
26
Natural rubber
latex based good for high friction abrasive applications but has low resistance to oil, heat and sunlight. App: shoes
27
Synthetic Rubber
improved environmental resistance over nat.rubber and higher temperature range. Apps: Tires, seals, belts
28
Silicones
Highes temperature range. but inferiour in other properties. App: Seals, gaskets, thermal insulation
29
Silicones
Highes temperature range. but inferiour in other properties. App: Seals, gaskets, thermal insulation
30
Processing of Polymers
Very similar to metals. Can be molded, cast, machined, joined with ease polymers require less energy to process but their properties are highly influenced by processes polymers start out in pellet form or as liquid for reinforced plastic parts
31
Polymer Extrusion
raw thermoplastic pellets are fed into the hopper and then a barrell. the barrel houses a screw that conveys the pellets down the barrel the shearing action as well as external heaters cause the pellets to melt in the last section of the screw the pressure builds up and a the polymer is extruded through a die
32
Extrusion Dies
Once the melted plastic reached the end of the barrel, it is forced through a die and cooled uniform cooling helps minimize distortion. various die shapes produce different proviles or even thin sheets and films. the phenomena of die swell causes plastic to be shaped differently than the extrusion die
33
Extrusion Dies
Once the melted plastic reached the end of the barrel, it is forced through a die and cooled uniform cooling helps minimize distortion. various die shapes produce different proviles or even thin sheets and films. the phenomena of die swell causes plastic to be shaped differently than the extrusion die
34
Co extrusion
h
35
Co extrusion
simultaneous extrusion of multiple polymers through a single die each material may have their own properties and funtions ie: barier to oil and water, electrical inslation and conduction, sealing and labelling plastic coated eletrcial wires are produced this way
36
Co extrusion
simultaneous extrusion of multiple polymers through a single die each material may have their own properties and funtions ie: barier to oil and water, electrical inslation and conduction, sealing and labelling plastic coated eletrcial wires are produced this way
37
Injection Molding (very common)
Similar to hot chamber die casting Polymer pellets are plasticized to create "the melt" the melt is forced through a nozzle into the mold Use a reciprocating screw type injector For thermoplastics - the mold is cooled to speed up processing. For thermosets -the mold is held got to promote polymerization and crossing linking shrinkage is a concern (1-7%) and molds are made oversized
38
Injection Mold Geometry
``` Gate Mold Cavity Cavities Main runners Sprue Guide Pin ```
39
Typesof Injection Molds
Cold Runner 2 plate Cold Runner 3 Plate Hot Runner Mold
40
Cold Runner 2 Plate
simplest mold desprue and runners must be removed by hand
41
Cold Runner 3 Plate
Runner system is removed from part via intermediate stripper plate Runners and parts are separate and solid
42
Hot Runner Mold
Runner system is kept in melted state after parts have solidified
43
Blow Molding
Combines Extrusion and injection molding
44
Extrusion Blow Molding
``` A thin tube (parison) is extruded and clamped into a mold high presure( 350-700 MPa) then forces the parison outward t fill the cavity. Upon coling the part is injected ```
45
Injection Blow Molding
Instrad of extruded parison in injected molded then transferred to a blow mold and expanded using high pressure gas. Ex: milk containers
46
Rotational Molding
similar to extrusion molding but at a lower cost Thin walled metal mold is made and powdered plastic is placed inside the mold. The heat and rotatin is applied about 2 perpendicular axis. Long thin walled parts may be made from this process. Cycle times are longer but mold and equipment costs are lower
47
Rotational Molding
similar to extrusion molding but at a lower cost Thin walled metal mold is made and powdered plastic is placed inside the mold. The heat and rotatin is applied about 2 perpendicular axis. Long thin walled parts may be made from this process. Cycle times are longer but mold and equipment costs are lower
48
Thermoforming
A family of processes where thermoplast sheet is formed over a mold via the application of heat and pressure or vacuum This plastic sheet is head until soft then placed over a mold and pressure is applied. Holld parts ma be made by forcing to plastic sheets together against the mold and applying force. Limitations: No parts with holes
49
Compression Molding
A preshaped charge i placed into a heated mold cavity and held under pressure until cured. Flash is formed which mustbe removed in subsequent operations Thermosets are usually chosen for compression molding because of londer cycle times and heated die molds are less complex and cost less tha injection molding undercuts are possible because molds can be mad to open sideways aps: dishes, handles, pipe fittings
50
Compression Molding
A preshaped charge i placed into a heated mold cavity and held under pressure until cured. Flash is formed which mustbe removed in subsequent operations Thermosets are usually chosen for compression molding because of londer cycle times and heated die molds are less complex and cost less tha injection molding undercuts are possible because molds can be mad to open sideways aps: dishes, handles, pipe fittings
51
Polymer Casting
Some thermoplastics and thermosets maybe cast into rigid or flexible molds. For thermoplasics a mixture of monomer and catalyst is poured into themold and allowe dto polymerize at ambient pressure Use flexible molds allow complex, intricate shapes to be formed inserts and other components may be cast into the patr allowing versatility form molding of cups, food containers and packing materials are made using this process