Polymers Flashcards

1
Q

Addition polymers are also known as?

A

polyalkenes

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2
Q

Which polymers are biodegradable and which are not? Why?

A

condensation polymers (polyesters and polyamides) are biodegradable as they can be broken down by hydrolysis due to the polarity within the polymer molecules

addition polymers (polyalkenes) are non-biodegradable because they are chemically inert and have non-polar (C-H and C-C) bonds

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3
Q

What are the 3 ways that condensation polymers are formed?

A

dicarboxylic acid + diol (polyesters)

dicarboxylic acid + diamine (polyamides)

amino acids (polypeptides which are also polyamides)

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4
Q

What is the polyester you have to know?

A

terylene (PET)

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5
Q

What are the polyamides you have to know?

A

nylon 6-6
kevlar

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6
Q

Typical uses of kevlar

A

bulletproof vests

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7
Q

Typical uses of nylon 6-6

A

clothing
carpets

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8
Q

Typical uses of terylene

A

plastic bottles
clothes

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9
Q

What is the amide linkage?

A

-CONH-

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10
Q

What is the ester linkage?

A

-COO-

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11
Q

Why can a single amino acid join to another to form a polymer?

A

because an amino acid has both a -NH and an -OH group

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12
Q

Why does hydrolysis break down condensation polymers?

A

the water molecules are attracted to the polar regions of the polymer

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13
Q

Why are condensation polymers strong?

A

they contain polar bonds so hydrogen bonds can form between separate chains

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14
Q

How can polyalkenes be broken down? Why is this bad?

A

by burning them
it produces harmful products (SO2, CO) which can also cause acid rain

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15
Q

Advantages of recycling

A

less waste in landfill
no need to derive new plastics from crude oil (expensive and finite resource)

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16
Q

Disadvantages of recycling

A

plastics needs to be collected, transported and sorted which requires energy so is expensive

17
Q

What are the ways to dispose of polymers?

A

landfill
burning
hydrolysis (condensation polymers only)

18
Q

Why do polyamides often have higher melting points than polyesters?

A

because polyamides can have hydrogen bonds between chains but polyesters cannot (and hydrogen bonds are the strongest type of IMF)