Polymers Flashcards

1
Q

Polymers

A
  1. Forms plastic and synthetic Fibers
  2. Long Chains formed from simple molecules (Monomers) joined together
  3. Monomers undergo reaction to link together and become a polymer by polymerisation
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2
Q

Types of Polymerisation Reaction

A
  1. Addition Polymerisation

2. Condensation Polymerisation

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3
Q

Addition Polymerisation

A
  1. Monomers must be Alkenes (Double Bonds)
  2. Double bond is broken and allows for addition of the next monomer unit
  3. The chain length can be tens of thousands long
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4
Q

Condensation Polymerisation

A
  1. Formed through a condensation reaction where molecules (Monomers) join together-losing small molecules as by-product (often water)
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5
Q

Thermosetting

A
  1. Thermosetting Plastic cannot be removed
  2. They don’t melt, they char
  3. Formed by a condensation reaction
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6
Q

Thermoplastic (Linear)

A
  1. Are polymers that form as long chains
  2. Long Chains = Large molecules with intermolecular Bonding
  3. Held by dispersion forces
  4. Heating the dispersion force can break and soften the material to mold into a new shape
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7
Q

Properties of the polymers are affected by

A
  1. Choice of monomer
  2. Degree of branching
  3. Degree of Crystallinity
  4. Length of polymer chain
  5. Addition of Plasticisers
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8
Q

Choice of Monomer

A
  1. An Addition polymer needs monomers with carbon double bonds.
  2. Condensation polymer has a molecule that’s eliminated in the Polymerisation Reaction
  3. Monomers can be the same or different
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9
Q

Degree of Crystallinity

A

Is how regularly aligned the polymer chains are; the more aligned the higher the degree of crytallinity

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10
Q

Additives

A
  1. Plasticizers - soften and increase flexibility
  2. UV stabilisers – absorb UV rays to prevent polymer breakdown
  3. flame retardants – reduce the likelihood of polymers burning
  4. Dyes – add color and/or patterns
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11
Q

Branching

A

With polyethylene there are two types
Low density (LDPE) and high density (HDPE)
Each are polyethylene but are produced under different conditions to have different properties and uses
LDPE is produced under higher pressure (20000psi) and moderate temperature (200C)
HDPE is produced under low pressure (200psi) and lower temperature (150C)

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12
Q

Advantages of LDPE

A
  1. High Elasticity/ Flexibility
  2. Soft
  3. Light Weight= Energy efficient
    4.
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13
Q

Disadvantages of LDPE

A
  1. Clear Plastic
  2. Flimsy and Thin
  3. Less strength then HDPE
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14
Q

Applications of LDPE

A

used in jobs that require more elasticity but limited strength

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15
Q

Advantages of HDPE

A
  1. Rigid and Firm
  2. Puncture Resistant
  3. Resistant to weather conditions
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16
Q

Disadvantages of HDPE

A
  1. Thicker Material
  2. Less Flexible
  3. Require more energy to produce
17
Q

Applications of HDPE

A

Jobs that require extra strength, but less flexibility