Polymers Flashcards
Polymers
- Forms plastic and synthetic Fibers
- Long Chains formed from simple molecules (Monomers) joined together
- Monomers undergo reaction to link together and become a polymer by polymerisation
Types of Polymerisation Reaction
- Addition Polymerisation
2. Condensation Polymerisation
Addition Polymerisation
- Monomers must be Alkenes (Double Bonds)
- Double bond is broken and allows for addition of the next monomer unit
- The chain length can be tens of thousands long
Condensation Polymerisation
- Formed through a condensation reaction where molecules (Monomers) join together-losing small molecules as by-product (often water)
Thermosetting
- Thermosetting Plastic cannot be removed
- They don’t melt, they char
- Formed by a condensation reaction
Thermoplastic (Linear)
- Are polymers that form as long chains
- Long Chains = Large molecules with intermolecular Bonding
- Held by dispersion forces
- Heating the dispersion force can break and soften the material to mold into a new shape
Properties of the polymers are affected by
- Choice of monomer
- Degree of branching
- Degree of Crystallinity
- Length of polymer chain
- Addition of Plasticisers
Choice of Monomer
- An Addition polymer needs monomers with carbon double bonds.
- Condensation polymer has a molecule that’s eliminated in the Polymerisation Reaction
- Monomers can be the same or different
Degree of Crystallinity
Is how regularly aligned the polymer chains are; the more aligned the higher the degree of crytallinity
Additives
- Plasticizers - soften and increase flexibility
- UV stabilisers – absorb UV rays to prevent polymer breakdown
- flame retardants – reduce the likelihood of polymers burning
- Dyes – add color and/or patterns
Branching
With polyethylene there are two types
Low density (LDPE) and high density (HDPE)
Each are polyethylene but are produced under different conditions to have different properties and uses
LDPE is produced under higher pressure (20000psi) and moderate temperature (200C)
HDPE is produced under low pressure (200psi) and lower temperature (150C)
Advantages of LDPE
- High Elasticity/ Flexibility
- Soft
- Light Weight= Energy efficient
4.
Disadvantages of LDPE
- Clear Plastic
- Flimsy and Thin
- Less strength then HDPE
Applications of LDPE
used in jobs that require more elasticity but limited strength
Advantages of HDPE
- Rigid and Firm
- Puncture Resistant
- Resistant to weather conditions