polymers Flashcards
What are polymers?
Long chain molecules made from joining short molecules called monomers together
examples of addition polymers
- poly(ethene)
- poly(propene)
- Perspex
- PVC
- Teflon
What do the properties of a polymer depend on?
- which monomers they are made from
- the conditions under which they are made
Ethene- use of polymer
- bags
- crates/boxes
chloroethene-use of polymer
- water pipes
- coating for window frames
propene-use of polymer
- carpets
- crates/boxes
tetrafluoroethene-use of polymer
- PTFE tape (used by plumbers)
- Non-stick coating in frying pans
Polymers with different properties can be made using the same monomer but by changing the reaction conditions. EG: Low density and high density polyethene are both made from the monomer ethene but under different conditions
Low density polyethene: -soft,flexible -uses: bags, cling film -monomer:ethene - reaction conditions: 200 degrees Celsius, 2000 atmosphere, catalyst: trace of oxygen High density polyethene -hard,strong -uses: buckets, water pipes -monomer: ethene -reaction conditions: 60 degrees Celsius, 2 atmospheres, Catalyst: Ziegla-Natta
Thermosoftening and thermosetting polymers
- The atoms within polymer chains are joined together by covalent bonds. In thermosoftening polymers, these polymer chains are not joined together
- In thermosetting polymers, the polymer chains are joined to each other by covalent bonds (often called cross-links
structure of thermosoftening polymer
- contains long polymer chains
- chains are not joined to each other (but they are tangled up with each other)
structure of thermosoftening polymer
- contains long polymer chains
- chains are joined to each other by covalent bonds (often called cross-links)
What happens when thermosoftening polymers are heated?
They soften and melt
Thermosetting polymer definition
A polymer with covalent bonds between polymer chains that does not soften or melt when heated.
What happens when thermosetting polymers are heated?
They do not soften or melt
thermosoftening polymer definition
A polymer with no bonds between polymer chains that softens and melts when heated
examples of thermosoftening polymers
- polyethene
- PVC
- Polypropene
- Perspex
- Teflon
- Polyesters
- Nylon
Examples of thermosetting polymers
- superglue
- epoxy resins
- melamine
- Bakelite
Glass
-It is used for windows and containers such as bottles
-It is a very useful material that is hard, see-through and unreactive
-there are many different types of glass with slightly different properties and uses:
eg:
.soda-lime glass
.Borosilicate glass
Soda-lime glass
What it is made from: sand, sodium carbonate, calcium carbonates
Uses: Windows, containers (eg: bottles)
Most of the glass we use is soda-lime glass
Borosilicate glass
What it is made from: sand, boron trioxide
uses: laboratory glassware, cookware (eg: glass pans)
.melts at a higher temperature than soda-lime glass
Clay ceramics
eg: bricks,pottery
- made by shaping wet clay that is then baked in a furnace or kiln
- clay ceramics are very hard, unreactive and resistant to heat.