Polymers 1 Flashcards
General Info
Largest class
Carbon-based in nature
Molecular weight (MW) is most important
Inexpensive
Manufacturing
Solution casting
Melt molding
Machining
Mers
Single chemical unit of a polymer
Monomer
Pendant Group
Side chain groups
Polymer classification
Origin Thermal props. Structure Chemical composition Conformation and config.
Origin
Natural - Cellulose, silk
Synthetic - PE, PVC
Thermal props. 1
Thermoplastic - soft upon heating (reversible)
Elastomers - flexible, harden on heating (rubbers)
Thermosets - hard upon heating, irreversible (PMMA)
Thermal props 2
Crystalline - melting temp
Amorphous - glass transition temp
Structure
Linear - Single backbone
Branched - Small side chain
Cross-linked - Network
Linear structure
Random coil
Rigid rod
Cyclic
Branched structure
Randomly
Comb
Star
Cross-linked structure
Also called gels Makes membranes Regular ladder Regular Spiro Irregular
Chemical composition
Homopolymer
Heteropolymer
Copolymer
Homopolymer
single RU monomer
Heteropolymer
Backbone is not all carbon