Polymers 1 Flashcards

1
Q

General Info

A

Largest class
Carbon-based in nature
Molecular weight (MW) is most important
Inexpensive

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2
Q

Manufacturing

A

Solution casting
Melt molding
Machining

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3
Q

Mers

A

Single chemical unit of a polymer

Monomer

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4
Q

Pendant Group

A

Side chain groups

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5
Q

Polymer classification

A
Origin
Thermal props.
Structure
Chemical composition
Conformation and config.
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6
Q

Origin

A

Natural - Cellulose, silk

Synthetic - PE, PVC

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7
Q

Thermal props. 1

A

Thermoplastic - soft upon heating (reversible)
Elastomers - flexible, harden on heating (rubbers)
Thermosets - hard upon heating, irreversible (PMMA)

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8
Q

Thermal props 2

A

Crystalline - melting temp

Amorphous - glass transition temp

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9
Q

Structure

A

Linear - Single backbone
Branched - Small side chain
Cross-linked - Network

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10
Q

Linear structure

A

Random coil
Rigid rod
Cyclic

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11
Q

Branched structure

A

Randomly
Comb
Star

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12
Q

Cross-linked structure

A
Also called gels
Makes membranes
Regular ladder
Regular Spiro
Irregular
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13
Q

Chemical composition

A

Homopolymer
Heteropolymer
Copolymer

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14
Q

Homopolymer

A

single RU monomer

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15
Q

Heteropolymer

A

Backbone is not all carbon

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16
Q

Copolymer

A

2 monomers

17
Q

Copolymer types

A

Block (AAABBBAAABBB)
Alternating (ABABAB)
Random

18
Q

Conformation and configuration

A

Location of side chains

Geometric isomers

19
Q

Geometric

A

Isotactic
Syndiotactic
Atactic

20
Q

Isotactic

A

Same side attached pendants

21
Q

Syndiotactic

A

Alternatively attached pendants

22
Q

Atactic

A

Randomly attached pendants

23
Q

Isomers

A

Double bond creating shape