Polymers 1 Flashcards
General Info
Largest class
Carbon-based in nature
Molecular weight (MW) is most important
Inexpensive
Manufacturing
Solution casting
Melt molding
Machining
Mers
Single chemical unit of a polymer
Monomer
Pendant Group
Side chain groups
Polymer classification
Origin Thermal props. Structure Chemical composition Conformation and config.
Origin
Natural - Cellulose, silk
Synthetic - PE, PVC
Thermal props. 1
Thermoplastic - soft upon heating (reversible)
Elastomers - flexible, harden on heating (rubbers)
Thermosets - hard upon heating, irreversible (PMMA)
Thermal props 2
Crystalline - melting temp
Amorphous - glass transition temp
Structure
Linear - Single backbone
Branched - Small side chain
Cross-linked - Network
Linear structure
Random coil
Rigid rod
Cyclic
Branched structure
Randomly
Comb
Star
Cross-linked structure
Also called gels Makes membranes Regular ladder Regular Spiro Irregular
Chemical composition
Homopolymer
Heteropolymer
Copolymer
Homopolymer
single RU monomer
Heteropolymer
Backbone is not all carbon
Copolymer
2 monomers
Copolymer types
Block (AAABBBAAABBB)
Alternating (ABABAB)
Random
Conformation and configuration
Location of side chains
Geometric isomers
Geometric
Isotactic
Syndiotactic
Atactic
Isotactic
Same side attached pendants
Syndiotactic
Alternatively attached pendants
Atactic
Randomly attached pendants
Isomers
Double bond creating shape