Polymer Structure Flashcards
What are the two types of polymers?
Thermoplastics or thermosoftening, and thermosets or thermosetting
Differentiate thermoplastic from thermosets
Thermoplastics are moldable, consist of tangled web polymer chains, and are attracted by weak - intermolecular forces, while thermosets cannot be melted once shaped, consist of cross links between molecules, and are attracted by strong - intramolecular forces.
What are the four types of polymer structure?
Linear, branched, crosslinked, and networked polymers
It resembles a spaghetti with long chains
Linear polymers (Thermoplastics)
There are shorter chains hanging from a spaghetti backbone and it tends to be less dense than linear polymers.
Branched polymers
It resembles ladders since the charge link from one bone to another and tied together by covalent bonding.
Ex. Hair structure - Disulfide bonds (SS)
Crosslinked polymers
These are complex polymers that are heavily linked to form network of 3D linkages. These are nearly impossible to soften when heating without degrading the underlying polymer structure.
Networked polymers (Thermosetting)
Long chains
Linear polymer
Held together by covalent bonding
Crosslinked polymer
Held together by weaker van der waals forces
Linear polymer