Polyesters Flashcards
condensation polymerisation is
the formation of a polymer, usually by the reaction of two different monomers, and in which s small molecule is also formed
in addition polymerisation, all/part of the atoms in the monomer molecules end up in the structure of the polymer
all atoms
the two main difference between condensation polymerisation and addition are:
- each time two monomer molecules join together, another small molecule is formed in condensation
- usually two different monomers react together in condensation
in many examples of condensation, the small molecule formed is
in other examples its
water
hydrogen chloride
when producing a polymer, we need two monomers, each with……………reactive group(s) at either end
two reactive groups, one at either end
alcohols usually involved in condensation reaction, as monomers, are more accurately known as….because
diols because they have an OH group at either end
as with the diols used as monomers, the carboxylic acid used as actually
dicarboxylic acids with a COOH group at either end of the molecule
the common name for the compound below is: (in the middle is a benzene structure)
_
HOOC - / O \ - COOH
\ _ /
terephthalic acid
when terephthalic acid reacts with ethandiol, the small molecule formed is……….as the ……. and the…..from the two monomers react
water
the OH from the dicarboxylic acid and the H from the alcohol react
we can also form polymers by using a…..instead of a dicarboxylic acid. this produces….as the small molecule, not water
dioyl chloride
hydrogen chloride produced