PMMA (acrylic resin) Flashcards
What usage errors can cause a denture to fail?
- fractures
- uncomfortable
- becomes warped
- surface suffers wear
- fits patient only for short period
what are the ideal properties of PMMA?
- dimensionally accurate and stable in use
- high softening temperature
- unaffected by oral fluids
what does stress/strain measure?
determines a materials stiffness
what determines the stress/strain of a material?
Young’s (elastic) Modulus
what are the ideal MECHANICAL properties of PMMA?
- high Young’s (elastic) modulus
* high proportional limit/elastic limit
what is meant by a high Young’s (elastic) modulus?
- material is rigid (stiff)
* applying a large stress produces a small strain !
what is meant by a high proportional limit/elastic limit?
• only large stresses will cause permanent deformation
what should the thermal expansion of PMMA match & why?
the artificial teeth to avoid internal stresses on cooling during manufacture
why is it important that a denture has a low density?
to aid retention of upper denture
how long has PMMA been around?
since about 1937
what type of setting reaction does PMMA undergo?
a free radical addition polymerisation
what is meant by a free radical addition polymerisation reaction?
chemical union of two molecules either the same or different to form a larger molecule WITHOUT the elimination of a smaller molecules
what type of bonding is seen in a free radical addition polymerisation reaction?
involves molecules with carbon to carbon double bonds (C=C)
what are the stages in the polymerisation of acrylic?
- activation
- initiation
- propagation
- termination
what is the activation stage of polymerisation?
activation of initiator to form free radicals