PMMA Flashcards
List ideal properties of a PMMA denture (7)
- Dimensionally accurate + stable
- High softening temp
- Unaffected by oral fluids
- Thermal expansion
- Low density
- Radiopaque
- Ideally show up on a radiograph - High thermal conductivity
List ideal properties of a PMMA denture in terms of how it looks (4)
- Non toxic/non irritant
- Colour/translucency
- Easy + inexpensive to manufacture
- Easy to repair
List mechanical properties a PMMA denture should display (4)
- High young elastic modulus
- High fatigue strength
- High impact strength
- High hardness/abrasion resistance
What kind of reaction does Acrylic resin undergo?
Free radical addition polymerisation
Involves C=C double bonds
What are the 4 steps of acrylic polymerisation?
- Activation
- Initiation
- Propagation
- Termination
What happens at the activation stage?
Activation of initiator to provide free radicals
What happens at the initiation stage?
Free radicals break the C=C bond and transfer the free radical
What happens at the propagation stage?
Propagation of the growing polymer chain
What happens at the termination stage?
Termination of polymerisation
What are the components of acrylic resin powder? (5)
- Initiator
- PMMA particles
- Plasticiser
- Pigments
- Co-polymers
What is the function of the plasticiser in acrylic resin powder?
Allows quicker dissolving in monomer liquid
What is the function of pigments in acrylic resin powder?
To give a natural colour
What is the initiator in acrylic resin powder?
Benzoyl peroxide
What is the function of co-polymers in acrylic resin powder+liquid?
To improve mechanical properties
What are the components of acrylic resin liquid? (3)
- Methacrylate Monomer
- Inhibitor (Hydroquinone)
- Co-polymers