Photosynthesis Flashcards
What is the chemical equation for photosynthesis?
6CO2 + 6H2O —> C6H12O6 + 6O2
What does light driven electron transport chains generate?
- ATP
- NADPH
- both needed to reduce CO2 to sugar
What are the two different types of photosynthesis?
Anoxygenic - electron donor is H2S (SO42-) - better e- donor - need only one photosystem to reduce NADP+ Oxygenic - electron donor is H2O (O2) - bad e- donor - needs 2 photosystems in series to reduce NADP+
Why are chlorophylls good at absorbing light?
- high extinction coefficient
Where is the gap in chlorophyll?
Huge absorbance gap where visible light is, hence why it does not absorb green and instead reflects
How does an organism that has chlorophyll fill the gap?
organism uses other pigments to fill the gap
- pigments phycocyanin and phycoerythrin in the 500-600nm wavelength region
- pigment carotenoids use for 400-500nm region
What happens when chlorophyls absorb light?
- becomes excited
- shifts redox potential to more negative value
What can bacteriochlorophylls do that normal chlorophylls cannot do?
- absorb in the infrared
What is the structure of the Phycobilin pigment?
- linear tetrapyrrole
- no Mg
- light harvesting complexes
What are the two functions of Carotenoids?
- protection from photooxidation
- light harvesting: not perfect but do fill gap
What happens once light is absorbed by a pigment?
- energy transfer from electron to the chlorophyll in the photosystem
- works better if the two electrons are closer together (<0.5nm)
(get 100% quantum yield)
How can you prevent fluorescence from happening?
- having a faster energy transfer than competing reactions
- photon emitted doesn’t have a longer wavelength than the photon absorbed
Name different energy transfer mechanisms from fastest to slowest?
fastest - delocalised exciton coupling
fast - resonance transfer (resonance between dipoles)
slowest - inductive resonance
What is the overall organisations of the light harvesting complexes?
- reaction centre in the middle containing light harvesting complex 1
- 2 chlorophylls - light harvesting complexes surround the reaction centre
- have multiple chlorophylls that orientate themselves in each light harvesting complex to absorb the most energy and get a fast transfer
- energy transferred onto the reaction centre
What are the different photosynthetic organism groups that undergo photosynthesis?
anoxygenic phototrophs - purple bacteria (proteobacteria) have photosystem 2 - green bacteria have photosystem 1 oxygenic phototrophs - cyanobacteria have both photosystems