Photochemical Rxn Flashcards

1
Q

Explain photo physical or photochemical rxn

A

R——–>R* ———–>I——–> P
<———– PHOTOCHEMICAL
PHOTOPHYSICAL

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2
Q

When we use uv light
When we use x, g ray

A

Photochemical rxn
Radiological rxn

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3
Q

L O R M I R U V X Y

A
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4
Q

Einstein drapper law states tha

A

One molecule absord one photon and 1 mole of reactant absord 1 mole of photon

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5
Q

Einstein ne iss process ko 2 step me divide kr diya

A

Primary process ( quantum yield =1)
Secondary process ( thermally controlled)

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6
Q

Quantum yield mole =

A

Nahc/lambda no. Of moles/total energy

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7
Q

Quantum yield =

A

hc/lambda× no. Of molecule related/ Et

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8
Q

E=

A

Power×time

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9
Q

10%of 40 joule energy

A

4 joule

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10
Q

Why the rate of fluorescence is faster than phospho or isc

A

Follow selection rule
Spin angular momentum =0
Spin angular momentum is conserved

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11
Q

Phosphorence

A

T1 TO S0
NOT FOLLOW SELECTION RULE
TAKES LONGER TIME

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12
Q

Singlet state decay occur by

A

IC
ISC
FLUORO

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13
Q

TrIplet state decay occur by

A

Phosphorescence

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14
Q

Explain quencher

A

Excited molecule ko ground state me laa deta hai

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15
Q

Parallel reaction

A

Reactant A changes to product B ,C

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