Photochemical Rxn Flashcards
Explain photo physical or photochemical rxn
R——–>R* ———–>I——–> P
<———– PHOTOCHEMICAL
PHOTOPHYSICAL
When we use uv light
When we use x, g ray
Photochemical rxn
Radiological rxn
L O R M I R U V X Y
Einstein drapper law states tha
One molecule absord one photon and 1 mole of reactant absord 1 mole of photon
Einstein ne iss process ko 2 step me divide kr diya
Primary process ( quantum yield =1)
Secondary process ( thermally controlled)
Quantum yield mole =
Nahc/lambda no. Of moles/total energy
Quantum yield =
hc/lambda× no. Of molecule related/ Et
E=
Power×time
10%of 40 joule energy
4 joule
Why the rate of fluorescence is faster than phospho or isc
Follow selection rule
Spin angular momentum =0
Spin angular momentum is conserved
Phosphorence
T1 TO S0
NOT FOLLOW SELECTION RULE
TAKES LONGER TIME
Singlet state decay occur by
IC
ISC
FLUORO
TrIplet state decay occur by
Phosphorescence
Explain quencher
Excited molecule ko ground state me laa deta hai
Parallel reaction
Reactant A changes to product B ,C