phospohrus Flashcards

1
Q

phosphorus os

A

+1, +4

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2
Q

oxides of nitrogen and phosphorus are

A

acidic

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3
Q

oxides of arsenic and antimony is

A

amphoteric

and of bismuth is basic

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4
Q

white p is

A

waxy translucent poisonous insoluble in h2o but soluble in CS2

all angles are 60

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5
Q

WHite p dissolves in naoh to give

it catches fire to give

A

PH3 and sodium hydrosulphite

P4O10

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6
Q

red p

A

obtained by heating white phosphorus at 573K
in an inert atmosphere for several days.

odourless, nonpoisonous
insoluble in water and in carbon disulphide

Chemically, red phosphorus is much less reactive than white
phosphorus. It does not glow in the dark.

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7
Q

alpha black p

A

α-Black phosphorus is formed when red phosphorus is heated in a sealed tube at 803K

opaque monoclinic or rhombohedral
crystals

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8
Q

beta black p

A

β-Black phosphorus is prepared by
heating white phosphorus at 473 K under high pressure. It does not
burn in air upto 673

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9
Q

phosgine prep

A

*calcium phosphide with water
or dilute HCl
* P4+NaOH+ H2O = PH3+ NaH2PO2

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