Phase Petrology 2 & 3 Flashcards
What happens in equlibrium crystallisazion?
The bulk composition of the liquid ends with the same proportion as the total solid composition
What does BC, LC and TSC mean?
BC = Bulk Composition
LC= Liquid Composition
TSC= Total solid composition
What does ISC mean?
Instantaneous solid composition
This is when fractionalized crystallization happens and a solid composition is formed, minerals are removed from the melt
Rules of crystallization
1) LC always moves radially away from ISC
2) TSC always moves towards the ISC
3) LC-BC-TSC are always colinear
4) Lever rule
Cotectic
“Co-crystallization” of two phases from the liquid (Univariant)
Ternary eutectics
“Co-crystallization” of three phases from the liquid (Invariant)
Gibbs Phase Rule
F=C+2-φ
F: Degrees of freedom
C: Components
φ: Equilibrium phases at a given O and T
Degrees of freedom
The number of system properties must be fixed to know all system (Phase) properties at eq.
What are the different degrees of freedom called?
F=2 : Divariant
F=1 : Univariant
F=0 : Invariant
Freezing point depression
T (Mixture) decreases with the addition of a new component to the liquid